Removal of ciprofloxacin from aqueous solutions by ionic surfactant-modified carbon nanotubes

Environmental Pollution
Haibo LiBaoshan Xing

Abstract

Ionic surfactants may impact removal efficiency of organic contaminants from aqueous solution, but research regarding the adsorption mechanisms on surfactant-modified carbon nanotubes (CNTs) was limited. In this study, three multi-walled and one single-walled CNTs were used as adsorbents to investigate the adsorption behavior and mechanisms of ciprofloxacin (CIP) on CNTs modified by ionic surfactants (cationic CTAB (Cetyltrimethylamnonium bromide) or anionic SDS (Sodium dodecyl sulfate)). More than 80% (82-88%) of the total removed CIP on CTAB-modified CNTs occurred within the first 6 h, much higher than that on SDS-modified CNTs (57-78%). Modeling adsorption kinetics demonstrated that CIP adsorption on surfactant-modified CNTs was controlled by multiple and faster processes, and both external mass transfer and intraparticle diffusion are limiting factors. Relative to SDS, CTAB was significantly (P < 0.001) concentration-dependent in suppressing CIP removal. Besides, the increase in 1/n values of Freundlich model with increasing CTAB concentration suggested that CTAB could be a stronger competitor for CIP adsorption. Hydrophobic interactions predominated zwitterionic CIP adsorption on all CNTs tested, while electrostatic interac...Continue Reading

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