Renaissance of pyridine-oxazolines as chiral ligands for asymmetric catalysis

Chemical Society Reviews
Guoqiang Yang, Wanbin Zhang

Abstract

Oxazoline-containing ligands have been widely employed in numerous asymmetric catalytic reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier than bisoxazoline and phosphine-oxazoline ligands; however, their unique properties have only been discovered recently. Pyridine-oxazoline-type chiral ligands are rapidly becoming popular for use in asymmetric catalysis, especially for several new and efficient asymmetric methodologies. Several types of challenging asymmetric reactions have been discovered recently using pyridine-oxazoline-type ligands showing their special properties and potential for future application in a wide range of new catalytic methodologies. This review provides an overview of this field, with the aim of highlighting both ligand design and synthetic methodology development.

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Citations

Aug 2, 2018·Chemical Communications : Chem Comm·Mao QuanWanbin Zhang
Nov 8, 2018·Chemistry : a European Journal·Nicholas J RaceMatthew S Sigman
Feb 12, 2019·Angewandte Chemie·Wang WangGuoyin Yin
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Jan 15, 2021·The Journal of Organic Chemistry·Peng-Peng NiuYu-Peng He
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Apr 15, 2020·The Journal of Organic Chemistry·Clemens BlasiusLutz H Gade

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Methods Mentioned

BETA
X-ray
diamination
hydroamination

Software Mentioned

Pyox

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