Research progress on polyoxometalate-based transition-metal-rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications

Chemical Communications : Chem Comm
Junwei ZhaoGuo-Yu Yang

Abstract

With the rapid development of science and technology and the trend of multidisciplinary pervasion, POM-based TM-RE heterometallic chemistry (POM = polyoxometalate, TM = transition-metal, RE = rare-earth) has become one of the most rapidly growing and challengeable areas of inorganic chemistry due to the impressive structural diversities, various chemical compositions and potential applications of these materials in magnetism, optics, electrochemistry, electrocatalysis and materials science. Over the past several years, continuous interest and persisting efforts have been dedicated to the preparation and exploration of POM-based TM-RE heterometallic derived materials (PTRHDMs), which have led to more than two hundred PTRHDMs. In this review, we summarize the structural types of reported PTRHDMs together with synthetic strategies, structural motifs and relevant functional applications. The exciting array of this emerging research theme presages continuous growth and great vitality. In the last section, some prospects of this branch are also presented and possible guidance for future work is outlined.

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Citations

Jul 21, 2016·Inorganic Chemistry·Feng LiEllen M Matson
May 9, 2018·Chemical Communications : Chem Comm·Miloš Đokić, Han Sen Soo
Jun 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Haiyan AnJianjun Zhang
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Feb 12, 2019·Chemical Communications : Chem Comm·Shujun LiXuenian Chen
Feb 27, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Huijie LiJunwei Zhao
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Jan 28, 2020·Chemistry : a European Journal·Jing Yang NiuJingping Wang
Sep 24, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Thomas Auvray, Ellen M Matson
Jan 23, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Hai-Long ZhangCan-Zhong Lu
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Aug 10, 2021·Chemical Communications : Chem Comm·Yu-Diao LinShou-Tian Zheng
Jun 27, 2018·Journal of the American Chemical Society·Brittney E PetelEllen M Matson

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