Reticular synthesis of covalent organic borosilicate frameworks

Journal of the American Chemical Society
Joseph R HuntOmar M Yaghi

Abstract

This paper reports the synthesis and characterization of a new crystalline 3D covalent organic framework, COF-202: [C(C6H4)4]3[B3O6 (tBuSi)2]4, formed from condensation of a divergent boronic acid, tetra(4-dihydroxyborylphenyl)methane, and tert-butylsilane triol, tBuSi(OH)3. This framework is constructed through strong covalent bonds (Si-O, B-O) that link triangular and tetrahedral building units to form a structure based on the carbon nitride topology. COF-202 demonstrates high thermal stability, low density, and high porosity with a surface area of 2690 m2 g-1. The design and synthesis of COF-202 expand the type of linkage that could be used to crystallize new materials with extended covalent organic frameworks.

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Citations

Dec 6, 2012·Journal of Molecular Modeling·Binit LukoseThomas Heine
May 19, 2012·Chemical Reviews·Dingcai WuKrzysztof Matyjaszewski
Aug 3, 2011·Journal of the American Chemical Society·Laura M LanniJohn J Lavigne
Jul 5, 2011·Journal of the American Chemical Society·Fernando J Uribe-RomoOmar M Yaghi
Aug 26, 2011·Journal of the American Chemical Society·Xuesong DingDonglin Jiang
Oct 27, 2011·Journal of the American Chemical Society·San-Yuan DingWei Wang
Oct 23, 2013·Journal of the American Chemical Society·Yue-Biao ZhangOmar M Yaghi
Nov 5, 2013·Journal of the American Chemical Society·Sasanka DalapatiDonglin Jiang
Mar 14, 2009·Journal of the American Chemical Society·Fernando J Uribe-RomoOmar M Yaghi
Jun 6, 2009·Journal of the American Chemical Society·Hiroyasu Furukawa, Omar M Yaghi
Dec 17, 2009·Journal of the American Chemical Society·Naoki NishimuraKenji Kobayashi
Dec 23, 2011·The Journal of Physical Chemistry. a·José L Mendoza-CortésWilliam A Goddard
Oct 14, 2011·The Journal of Physical Chemistry. a·Jose L Mendoza-CortesWilliam A Goddard
May 23, 2013·Nature Chemistry·John W Colson, William R Dichtel
Dec 3, 2010·Nature Chemistry·Christian J DoonanOmar M Yaghi
Jul 24, 2010·Nature Chemistry·Eric L Spitler, William R Dichtel
Jul 1, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Kay Severin
Jan 23, 2013·Physical Chemistry Chemical Physics : PCCP·Jing-hua GuoXinlu Cheng
Apr 24, 2013·Physical Chemistry Chemical Physics : PCCP·Jing-Hua GuoYoshiyuki Miyamoto
Jan 1, 2010·Beilstein Journal of Nanotechnology·Binit LukoseThomas Heine
Jul 2, 2014·Journal of Molecular Modeling·Wenliang LiJingping Zhang
Dec 24, 2015·Journal of the American Chemical Society·Mona CalikThomas Bein
Mar 2, 2016·Journal of the American Chemical Society·Guiqing LinCheng Wang
Nov 19, 2015·Accounts of Chemical Research·Peter J WallerOmar M Yaghi
Oct 13, 2015·Scientific Reports·Xiong ChenDonglin Jiang
Oct 19, 2016·Journal of the American Chemical Society·Hui LiShilun Qiu
Feb 10, 2011·PLoS Computational Biology·Maria D Chikina, Olga G Troyanskaya
Dec 31, 2016·Chemical Reviews·Saikat DasShilun Qiu
Jun 9, 2017·Journal of the American Chemical Society·Guiqing LinCheng Wang
Jun 20, 2017·ACS Applied Materials & Interfaces·Manman MuLigong Chen
Jun 10, 2016·Physical Chemistry Chemical Physics : PCCP·Pierre Fayon, Abbie Trewin
Jul 26, 2017·Advanced Materials·Lanfang ZouHong-Cai Zhou
Dec 29, 2017·Nanomaterials·Fuli ZhaoJianhua Zhang
Nov 22, 2014·Physical Chemistry Chemical Physics : PCCP·Christian ReeceAbbie Trewin
Nov 17, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Hedi Karoui, Chris Ritchie
Nov 7, 2017·Angewandte Chemie·Yuanyuan ZhangBo Wang
Feb 26, 2013·Angewandte Chemie·Atsushi NagaiDonglin Jiang
Feb 22, 2013·Angewandte Chemie·Antonio AvellanedaChristian J Doonan
Feb 7, 2013·Chemistry : a European Journal·Mohammad Gulam RabbaniHani M El-Kaderi
Feb 18, 2009·Macromolecular Rapid Communications·Arne ThomasMarkus Antonietti

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