Rh(I)-catalyzed decarboxylative transformations of arenecarboxylic acids: ligand- and reagent-controlled selectivity toward hydrodecarboxylation or Heck-Mizoroki products

Organic Letters
Zhong-Ming SunPinjing Zhao

Abstract

A Rh(I)-based catalyst system has been developed to promote three types of decarboxylative transformations of arenecarboxylic acids: (1) hydrodecarboxylation, (2) Heck-Mizoroki olefination, and (3) conjugate addition. Scopes of reactions (1) and (2) were studied, and the ligand and reagent dependence of selectivity was explored.

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