Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles.

Organic Letters
Yajing Lian, Huw M L Davies

Abstract

An unusual rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles is described. These studies show that (Z)-vinylcarbenoids have a greater tendency than (E)-vinylcarbenoids to react at the vinylogous position of the carbenoid rather than at the carbenoid center.

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Citations

Jan 27, 2011·Journal of the American Chemical Society·Andrew DeAngelisJoseph M Fox
Dec 24, 2010·Journal of the American Chemical Society·Barry M TrostJoseph M Azzarelli
Sep 22, 2011·Journal of the American Chemical Society·Xiaochen WangMichael P Doyle
Jul 25, 2017·Natural Product Reports·Wenhan Zhang, Joseph M Ready
Oct 20, 2012·Angewandte Chemie·Appaso Mahadev JadhavRai-Shung Liu
Mar 5, 2014·Angewandte Chemie·Sudam Ganpat DawandeSreenivas Katukojvala
Jan 8, 2020·Angewandte Chemie·Bowen Zhang, Huw M L Davies
Jul 19, 2012·Angewandte Chemie·Damien ValetteHuw M L Davies
Mar 3, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Mandeep Kaur HunjanJoydev K Laha
Oct 13, 2010·Organic Letters·Michael B Johansen, Michael A Kerr
Sep 13, 2013·Journal of the American Chemical Society·Changming Qin, Huw M L Davies
May 7, 2013·The Journal of Organic Chemistry·Vinayak Vishnu PagarRai-Shung Liu
Jan 7, 2015·Journal of the American Chemical Society·Atsushi D YamaguchiHuw M L Davies
Mar 10, 2011·Journal of the American Chemical Society·Jørn H HansenHuw M L Davies

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