Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

Angewandte Chemie
Masao MorimotoMasahiro Murakami

Abstract

Aliphatic terminal alkenes react with pinacolborane at ambient temperature to afford dehydrogenative borylation compounds as the major product when iPr-Foxap is used as the ligand with cationic rhodium(I) in the presence of norbornene, which acts as the sacrificial hydrogen acceptor. The reaction is applied to the one-pot syntheses of aldehydes and homoallylic alcohols from aliphatic terminal alkenes.

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Apr 23, 2016·Journal of the American Chemical Society·William B ReidDonald A Watson
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Jan 23, 2020·Journal of the American Chemical Society·Lewis B SmithTimothy J Donohoe
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