Rhodium(I)-Catalyzed Tertiary Phosphine Directed C-H Arylation: Rapid Construction of Ligand Libraries

Angewandte Chemie
Xiaodong QiuZhuangzhi Shi

Abstract

Modification of commercially available monophosphine ligands with either aryl bromides or chlorides by rhodium(I)-catalyzed, tertiary phosphine directed C-H activation is described. A series of ligand libraries containing mono- and diaryl-substituted groups, having different steric and electronic properties, were obtained in high yields. Based on the outstanding properties of their parent scaffolds, the modified ligands have been found to be powerful in organic reactions.

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Citations

May 19, 2018·Chemical Communications : Chem Comm·Zhuan ZhangJean-François Soulé
Jul 24, 2018·Chemical Society Reviews·Carlo SambiagioMichael Schnürch
Oct 6, 2018·Chemistry : a European Journal·Mario MarínErnesto Carmona
Jan 8, 2019·Angewandte Chemie·Jian WenZhuangzhi Shi
Jan 22, 2019·Angewandte Chemie·Kazuishi FukudaJun Takaya
Mar 28, 2019·Chemical Communications : Chem Comm·Eva DeckFrank Breher
Feb 6, 2020·Chemistry : a European Journal·Guang-Ao YuChang-Duo Yue
Dec 18, 2018·Science Advances·Xiaodong QiuZhuangzhi Shi
Jan 15, 2021·The Journal of Organic Chemistry·Peng-Peng NiuYu-Peng He
Feb 26, 2021·Organic Letters·Hui-Bei XuLin Dong
Mar 13, 2021·Accounts of Chemical Research·Jian Wen, Zhuangzhi Shi
Jun 17, 2021·Organic & Biomolecular Chemistry·Dhanashri A SableBhalchandra M Bhanage
Apr 26, 2019·Organic Letters·Yuzhen GaoGang Li
Apr 9, 2019·Organic Letters·Jia-Wei LiMing-Hua Zeng
May 5, 2018·Journal of the American Chemical Society·Arun Jyoti Borah, Zhuangzhi Shi
Apr 9, 2020·Journal of the American Chemical Society·Shengyi YanShao-Hua Xiang
Sep 24, 2021·Organic & Biomolecular Chemistry·Zixian YangChangduo Pan
Dec 9, 2021·Chemistry : a European Journal·Jiahang LvZhuangzhi Shi

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