Robust hydrogen-bonded self-assemblies from biimidazole complexes. Synthesis and structural characterization of [M(biimidazole)2(OH2)2]2+ (M = Co2+, Ni2+) complexes and carboxylate modules

Dalton Transactions : an International Journal of Inorganic Chemistry
Reinaldo AtencioAnibal Sierraalta

Abstract

A robust heteromeric hydrogen-bonded synthon [R2(2) (9)-Id] is exploited to drive the modular self-assembly of four coordination complexes [M(H2biim)2(OH2)2]2+ (M = Co2+, Ni2+) and carboxylate counterions. This strategy allowed us to build molecular architectures of 0-, 1-, and 2-dimensions. A hydrogen-bonded 2D-network with cavities has been designed, which maintains its striking integrity after reversible water desorption-resorption processes.

References

Apr 4, 2002·Proceedings of the National Academy of Sciences of the United States of America·Makoto TadokoroKazuhiro Nakasuji
May 31, 2002·Acta Crystallographica. Section B, Structural Science·Frank H Allen
Feb 15, 1999·Angewandte Chemie·Owen R EvansWenbin Lin

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Citations

Mar 16, 2006·Chemical Communications : Chem Comm·Makoto TadokoroKazuhiro Nakasuji
Dec 17, 2008·Chemical Communications : Chem Comm·Rui-Li Sang, Li Xu
Jan 1, 2009·Acta Crystallographica. Section E, Structure Reports Online·Tingting ZhangHongze Liang
Jan 27, 2005·Chemical Communications : Chem Comm·Reinaldo AtencioXacvier Galindo
Dec 13, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Sofia DerossiMichael D Ward
Dec 15, 2005·Chemical Communications : Chem Comm·Laura IonMary McPartlin
Jun 27, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Ankita DasGoutam Kumar Lahiri
Jul 20, 2012·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Makoto TadokoroTomoaki Sugaya
Jan 28, 2010·The Journal of Physical Chemistry. B·Makoto TadokoroKuroki Ryota

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