Role of Crystal Symmetry in the Reversibility of Stacking-Sequence Changes in Layered Intercalation Electrodes

Nano Letters
Maxwell D RadinAnton Van der Ven

Abstract

The performance of many technologies, such as Li- and Na-ion batteries as well as some two-dimensional (2D) electronics, is dependent upon the reversibility of stacking-sequence-change phase transformations. However, the mechanisms by which such transformations lead to degradation are not well understood. This study explores lattice-invariant shear as a source of irreversibility in stacking-sequence changes, and through an analysis of crystal symmetry shows that common electrode materials (graphitic carbon, layered oxides, and layered sulfides) are generally susceptible to lattice-invariant shear. The resulting irreversible changes to microstructure upon cycling ("electrochemical creep") could contribute to the degradation of the electrode and capacity fade.

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Citations

Jul 10, 2019·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·Jonas L KaufmanAnton Van der Ven
May 24, 2019·Angewandte Chemie·Sanghan LeeJaephil Cho
Jun 20, 2020·Chemical Communications : Chem Comm·Yuji IshadoMasaki Matsui
Jan 14, 2021·Scientific Reports·Ravuri SyamsaiAndrews Nirmala Grace
Aug 3, 2021·The Journal of Physical Chemistry Letters·Jon Serrano-SevillanoAmaia Saracibar
Aug 29, 2019·ACS Omega·Roberta VerrelliM Rosa Palacín
Apr 2, 2019·Journal of the American Chemical Society·Lufeng YangHailong Chen
Feb 6, 2020·Chemical Reviews·Anton Van der VenShyue Ping Ong
Oct 30, 2019·Chemical Reviews·M Elena Arroyo-de DompabloM Rosa Palacín
Nov 5, 2020·Journal of the American Chemical Society·Xiang LiuKhalil Amine

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