Role of Cu in Mo₆S₈ and Cu mixture cathodes for magnesium ion batteries

ACS Applied Materials & Interfaces
Seung-Hyun ChoiYoung-Jun Kim

Abstract

The reversible capacity of Chevrel Mo6S8 cathode can be increased by the simple addition of the Cu metal to Mo6S8 electrodes. However, the exact reaction mechanism of the additional reversible capacity for the Mo6S8 and Cu mixture cathode has not been clearly understood yet. To clarify this unusual behavior, we synthesize a novel Cu nanoparticle/graphene composite for the preparation of the mixture electrode. We thoroughly investigate the electrochemical behaviors of the Mo6S8 and Cu mixture cathode with the relevant structural verifications during Mg(2+) insertion and extraction. The in situ formation of Cu(x)Mo6S8 is observed, indicating the spontaneous electrochemical insertion of Cu to the Mo6S8 host from the Cu nanoparticle/graphene composite. The reversible electrochemical replacement reaction of Cu in the Mo6S8 structure is clarified with the direct evidence for the solid state Cu deposition/dissolution at the surface of Mo6S8 particles. Moreover, the Mo6S8 and Cu mixture cathode improves the rate capability compared to the pristine. We believe that our finding will contribute to understanding the origin of the additional capacity of the Mo6S8 cathode arising from Cu addition and improve the electrochemical performance o...Continue Reading

References

Oct 26, 2000·Nature·D AurbachE Levi
Mar 8, 2011·Chemical Reviews·Zhenguo YangJun Liu
Jan 9, 2013·Journal of the American Chemical Society·John B Goodenough, Kyu-Sung Park

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Citations

Oct 20, 2017·ACS Applied Materials & Interfaces·Nan WangJiulin Wang
Feb 14, 2019·ACS Applied Materials & Interfaces·Yuanying YangJiulin Wang
Mar 9, 2017·Chemical Reviews·Pieremanuele CanepaGerbrand Ceder

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