Roles of metal, ligand and post synthetic modification on metal organic frameworks to extend their hydrophobicity and applicability toward ultra-trace determination of priority organic pollutants

Analytica Chimica Acta
Hasan JavanmardiHabib Bagheri

Abstract

Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF-5 families were chosen, and eleven MOF-based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL-101 and MIL-101-NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc-based structures including MOF-5, [NH2(CH3)2]2 [Zn3(C6H4(CO2)2)4].DMF.H2O and [NH2(CH3)2]2 [Zn3((C6H4)2(CO2)2)4].5DMF were synthesized. The PSM hydrophobic-oriented products of MILs were obtained by their reactions with benzyl alcohol. The resulted MOFs were characterized by FT-IR, PXRD, SEM, BET, BJH, water contact angle and TG analyses. The extraction trends of these nanostructures were studied toward some priority environmental pollutants such as polycyclic aromatic hydrocarbons (PAHs), chlorobenzenes (CBs), and benzene homologs. The extraction procedures were performed via adapting a home-made h...Continue Reading

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry
Natalia ManousiGeorge A Zachariadis
Environmental Science and Pollution Research International
Natalia ManousiEleni A Deliyanni
© 2021 Meta ULC. All rights reserved