Room temperature olefination of methane with titanium-carbon multiple bonds

Chemical Science
Takashi KurogiDaniel J Mindiola

Abstract

C-H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H2C 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 000...Continue Reading

References

Aug 29, 2013·Journal of the American Chemical Society·Marco G CrestaniDaniel J Mindiola
May 21, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Anne K HickeyDaniel J Mindiola
Mar 3, 2017·Chemical Communications : Chem Comm·Takashi KurogiDaniel J Mindiola

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Citations

Dec 12, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Hui LiuXiaochao Shi
Dec 15, 2018·Angewandte Chemie·Hassan OsseiliJun Okuda
Nov 17, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Celia IdelsonF Mark Chadwick
Sep 16, 2020·Inorganic Chemistry·Jonas C OttLutz H Gade
Dec 2, 2021·The Journal of Physical Chemistry Letters·Lei WuShaodong Zhou

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Methods Mentioned

BETA
X-ray
NMR

Software Mentioned

MO

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