Ruthenium complexes with dendritic ferrocenyl phosphanes: synthesis, characterization, and application in the catalytic redox isomerization of allylic alcohols

Chemistry : a European Journal
Paul NeumannEvamarie Hey-Hawkins

Abstract

An efficient system for the catalytic redox isomerization of the allylic alcohol 1-octen-3-ol to 3-octanone is presented. The homogeneous ruthenium(II) catalyst contains a monodentate phosphane ligand with a ferrocene moiety in the backbone and provides 3-octanone in quantitative yields. The activity is increased by nearly 90 % with respect to the corresponding triphenyl phosphane ruthenium(II) complex. By grafting the catalyst at the surface of a dendrimer, the catalytic activity is further increased. By introducing different spacers between ferrocene and phosphorus, the influence on the electronic properties of the complexes is shown by evaluating the electrochemical behavior of the compounds.

References

Sep 15, 1988·Physical Review A: General Physics·A D Becke
Jun 15, 1986·Physical Review. B, Condensed Matter·J P Perdew
Dec 26, 2001·Chemical Reviews·J P Majoral, A M Caminade
Dec 25, 2003·Journal of the American Chemical Society·Pavel I Kitov, David R Bundle
Nov 27, 2004·Organic & Biomolecular Chemistry·Alart MulderDavid N Reinhoudt
Aug 11, 2005·Chemistry : a European Journal·Kazuya YamaguchiNoritaka Mizuno
Dec 25, 2007·Acta Crystallographica. Section A, Foundations of Crystallography·George M Sheldrick
Jan 17, 2008·Chemical Society Reviews·Anne-Marie CaminadeJean-Pierre Majoral
Jun 3, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul ServinAnne-Marie Caminade
Dec 1, 2010·Chemical Society Reviews
Mar 10, 2011·The Journal of Chemical Physics·Steve Scheiner
Apr 20, 2011·Chemistry : a European Journal·Stefan ZahnBarbara Kirchner
Jan 5, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Nanna AhlstenBelén Martín-Matute
Nov 20, 2013·The Journal of Physical Chemistry. a·K Eskandari, N Mahmoodabadi
Nov 22, 2014·Angewandte Chemie·Paul NeumannEvamarie Hey-Hawkins

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Citations

Apr 28, 2016·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Anne-Marie Caminade, Jean-Pierre Majoral
Jul 1, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Daniel D SwansonSeth N Brown
Jun 21, 2018·Chemistry : a European Journal·Antonin DesmechtOlivier Riant
Jan 25, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Cédric-Olivier TurrinAnne-Marie Caminade
Feb 13, 2020·Chemistry : a European Journal·John PoppEvamarie Hey-Hawkins
Oct 8, 2016·Chemistry : a European Journal·Matea VlatkovićBen L Feringa
Oct 22, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Axel StraubeEvamarie Hey-Hawkins
Jun 8, 2021·Chemical Science·Axel StraubeEvamarie Hey-Hawkins

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