Selective metal substitution for the preparation of heterobimetallic microporous coordination polymers

Inorganic Chemistry
Stephen R Caskey, Adam J Matzger

Abstract

The designed synthesis of heterobimetallic microporous coordination polymers (MCPs) is reported by a strategy employing the selective replacement of a single metal in homometallic MCPs with two unique metal coordination environments: octahedral and tetrahedral. This strategy is successful in the preparation of six mixed-metal MCPs, where Co/Zn and Ni/Zn versions of MOF-4, MOF-39, and a Zn-BTEC MCP are reported.

References

Feb 22, 2003·Angewandte Chemie·Bin ZhaoGeng-Lin Wang
Nov 26, 2004·Journal of the American Chemical Society·Bin ZhaoZong-Hui Jiang
Mar 15, 2006·Angewandte Chemie·Adam L GrzesiakAdam J Matzger
Nov 23, 2006·Journal of the American Chemical Society·Sara R HalperSeth M Cohen
Feb 3, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Yonghui WangDirk Volkmer
Mar 16, 2007·Inorganic Chemistry·Feng-Qin WangLin-Pei Jin
Apr 27, 2007·Inorganic Chemistry·Ying WangShi-Ping Yan
Jul 5, 2007·Angewandte Chemie·Carine LivageGérard Férey
Jul 14, 2007·Inorganic Chemistry·Bangbo Yan, Paul A Maggard
Oct 2, 2007·Journal of the American Chemical Society·Bangbo YanPaul A Maggard
Oct 4, 2007·Chemistry : a European Journal·Jian-Wen ChengGuo-Yu Yang
Dec 7, 2007·Angewandte Chemie·Kyoungmoo KohAdam J Matzger

❮ Previous
Next ❯

Citations

Jul 22, 2011·Chemical Communications : Chem Comm·Dong HanMao-Chun Hong
Sep 25, 2012·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Nagendra K KaushikRajeev Gupta
Oct 28, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Min-Le HanJun Zhao
Apr 1, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhou ZhaoShourong Zhu
Apr 13, 2019·Angewandte Chemie·Mohammad Yaser MasoomiHermenegildo Garcia
Dec 19, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Christina A BauerMark D Allendorf
Aug 12, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Richa RajakShaikh M Mobin
Oct 23, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Gia-Thanh VuongTrong-On Do
Apr 5, 2014·Chemistry : a European Journal·Shin Ae ParkMoonhyun Oh
Feb 2, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Partha MahataSrinivasan Natarajan
Feb 15, 2011·Chemistry : a European Journal·Jianyong ZhangCheng-Yong Su
Jun 25, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Yun-Wu LiXian-He Bu
Jan 24, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Yaroslaw D LampekaVladimir B Arion
Feb 26, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Aleksandr A SapianikVladimir P Fedin
Feb 4, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Aleksandr A SapianikVladimir P Fedin
Apr 28, 2020·Chemical Science·Liyu ChenQiang Xu

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.