Selective metalation of phenol-type proligands for preparative organometallic chemistry

Chemical Communications : Chem Comm
Andreas BerkefeldHartmut Schubert

Abstract

The selective C-metalation of phenol ester derived proligands is a readily applicable addition to state-of-the-art protocols toward cyclometalated structures, in particular of the base metals. The approach is demonstrated by the ortho-nickelation of a 1,10-phenanthroline based strong-field ligand platform that is a sought-after motif in the field of base-metal photochemistry.

References

Jan 24, 1997·The Journal of Organic Chemistry·Anny Jutand, Adil Mosleh
Apr 10, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·J A Gareth WilliamsVictoria L Whittle
Jul 9, 2008·Chemical Reviews·Anny Jutand
Dec 8, 2010·Chemical Reviews·Brad M RosenVirgil Percec
Mar 21, 2013·Chemical Reviews·Christopher K PrierDavid W C MacMillan
Aug 27, 2014·Chemical Society Reviews·Josep CornellaRuben Martin
Dec 23, 2014·Inorganic Chemistry·Sriparna MukherjeeElena Jakubikova
Jun 17, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Isabelle M DixonJean-Louis Heully
Aug 2, 2016·Inorganic Chemistry·Linda S JongbloedJarl Ivar van der Vlugt
Nov 14, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Loïc P Mangin, Davit Zargarian
Jun 26, 2018·European Journal of Inorganic Chemistry·Linda S JongbloedJarl Ivar van der Vlugt
Aug 15, 2018·Angewandte Chemie·Gwilherm Evano, Cédric Theunissen
Sep 22, 2018·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Ashish A MishraBhalchandra M Bhanage
Nov 28, 2018·Chemical Reviews·Parthasarathy GandeepanLutz Ackermann
Mar 8, 2019·Chemical Reviews·Andreas A DanopoulosPierre Braunstein

❮ Previous
Next ❯

Citations

Feb 27, 2021·Journal of the American Chemical Society·Hannah KurzBirgit Weber
Mar 11, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexander HaseloerAxel Klein

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray
NMR

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Beilstein Journal of Organic Chemistry
Bernd F StraubLutz H Gade
Schweizer Monatsschrift für Zahnmedizin = Revue mensuelle suisse d'odonto-stomatologie = Rivista mensile svizzera di odontologia e stomatologia
A Wiskott
© 2021 Meta ULC. All rights reserved