Selective oxidative decarboxylation of amino acids to produce industrially relevant nitriles by vanadium chloroperoxidase

ChemSusChem
Andrada ButJohan P M Sanders

Abstract

Industrial nitriles from biomass: Vanadium-chloroperoxidase is successfully used to transform selectively glutamic acid into 3-cyanopropanoic acid, a key intermediate for the synthesis of bio-succinonitrile and bio-acrylonitrile, by using a catalytic amount of a halide salt. This clean oxidative decarboxylation can be applied to mixtures of amino acids obtained from plant waste streams, leading to easily separable nitriles.

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Jul 9, 2008·ChemSusChem·Claus Hviid ChristensenKresten Egeblad
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Citations

Aug 31, 2013·Chemical Reviews·Adrie J J Straathof
Jun 7, 2014·Chemical Communications : Chem Comm·Dirk HoltmannFrank Hollmann
Apr 10, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Dieter Rehder
Mar 23, 2013·Chemical Society Reviews·Maurice C R FranssenJohan P M Sanders
Apr 4, 2017·Chemical Communications : Chem Comm·Jasper Verduyckt, Dirk E De Vos
Mar 25, 2018·Angewandte Chemie·JiaJia DongWuyuan Zhang
Feb 16, 2019·ChemSusChem·Daniel MackElias Klemm
Oct 11, 2019·Organic & Biomolecular Chemistry·Georg T HöflerFrank Hollmann
Mar 3, 2020·ACS Sustainable Chemistry & Engineering·Georg T HöflerFrank Hollmann

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