Abstract
In the present communication, a non-covalent fenarimol-imprinted polymer was synthesized by precipitation polymerization technique using methacrylic acid (MAA) as a functional monomer, ethylene glycol dimethacrylate (EGDMA) as a cross-linker, and azobisisobutyronitrile (AIBN) as an initiator in different porogenic solvent. Binding study of molecularly imprinted and non-imprinted polymer (MIP and NIP) showed that MIP possesses a higher affinity towards this analyte compared to NIP. The binding affinity of MIP was calculated by static and kinetic adsorption study. Further, a MIP based cartridge was designed to use in extraction process, necessary for specific determination and quantification of the fungicide in food matrices. Under the optimum conditions, developed method was found to be linear (R(2)=0.9999-0.9994). Limit of detection (LOD) and limit of quantitation (LOQ) in samples were 0.03-0.06 and 0.12-0.21 μg mL(-1), respectively. The rate of recovery of fenarimol was 91.16-99.52% on MIPs. The validated method of molecularly imprinted solid-phase extraction (MISPE) cartridge was successfully applied to the food matrices and compared with commercial sorbent (RP18 and Oasis HLB). However we feel, this method has promising appl...Continue Reading
References
Mar 29, 1996·Cancer Letters·M PaoliniG Cantelli-Forti
Jan 10, 2002·Chemical Reviews·Günter Wulff
May 14, 2003·Forensic Science International : Synergy·P ProençaD N Vieira
Apr 6, 2004·Analytical and Bioanalytical Chemistry·Lei Ye, Karsten Haupt
Apr 20, 2004·Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences·Norbert M MaierWolfgang Lindner
Dec 14, 2004·Toxicology·Anne Marie VinggaardChristine Nellemann
Oct 31, 2006·Reproductive Toxicology·Vera L S S de CastroPaola Poli
Feb 23, 2007·Journal of Chromatography. a·Kathy RidgwayRoger M Smith
Oct 20, 2009·Talanta·Xingliang SongLingxin Chen
Mar 11, 2011·Journal of Chromatography. a·Hongyuan YanGengliang Yang
Nov 1, 1996·Analytical Chemistry·A G Mayes, K Mosbach
Jun 4, 2011·Journal of Chromatography. a·Luca CamponeLuca Rastrelli
Jun 28, 2011·Journal of Chromatography. a·María Asensio-RamosJavier Hernández-Borges
Mar 29, 2013·Bioanalysis·Mohana Krishna Reddy MudiamPrem Narain Saxena
Apr 9, 2013·Food Chemistry·Wei DuChun Chang
Sep 24, 2013·Talanta·Yu-Long WangXiu-Juan Li
Jan 28, 2015·Food Chemistry·Yaxi HuXiaonan Lu
Feb 11, 2015·Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences·Abhishek ChauhanMohana Krishna Reddy Mudiam
Citations
Oct 23, 2016·Analytica Chimica Acta·Jiankun CaoFengxia Qiao
Jan 14, 2017·Journal of Agricultural and Food Chemistry·Huilin LiuBaoguo Sun
Apr 30, 2017·Journal of Separation Science·Die GaoZhi-Ning Xia
Apr 21, 2018·Electrophoresis·Edvaldo V Soares MacielFernando Mauro Lanças
Nov 2, 2018·The Analyst·Zulei ZhangLei Li
Apr 25, 2018·Journal of Chromatographic Science·Abubakar LawalAli Mohamed Ali Alsharif
Jul 8, 2020·Journal of Molecular Modeling·Xusheng HuangZhaojun Xian
Sep 25, 2018·Chemical Reviews·Joseph J BelBruno