Self-assembly of a series of novel metal-organic compounds containing ferrocenecarboxylate components

Inorganic Chemistry
Hongwei HouYu Zhu

Abstract

Using FcCOONa (Fc = (eta(5)-C(5)H(5))Fe(eta(5)-C(5)H(4))) as starting material, we obtained an unprecedented metal-organic coordination polymer containing ferrocenecarboxylate components [[Pb(2)(FcCOO)(eta(2)-FcCOO)(mu(2)-eta(2)-FcCOO)(mu(3)-eta(2)-FcCOO)(CH(3)OH)].1.5CH(3)OH.H(2)O](n) (1), tetramer [Zn(4)(mu(2)-FcCOO)(6)(mu(4)-O)] (2), and coordination polymers [Pb(FcCOO)(mu(2)-FcCOO)(bpe)](n) (3) (bpe = 1,2-bis(4-pyridyl)ethene), [[Zn(FcCOO)(2)(bpt)].2.5H(2)O](n) (4) (bpt = N,N'-bis(3-pyridylmethyl)thiourea), and [Zn(FcCOO)(eta(2)-FcCOO)(bbp)](n) (5) (bbp = 4,4'-trimethylene-dipyridine). Compounds 1 and 2 are formed by ferrocenecarboxylate units coordinating with Pb(II) or Zn(II). In polymer 1, ferrocenecarboxylate units have four kinds of coordinate modes; just these novel coordinate modes lead to the unprecedented one-dimensional polymer where two kinds of rhomboids are arranged alternatively along the chain. Compound 2 is a tetramer, in which a distinct connectivity of the six ferrocene units is established through the four Zn atoms. Compounds 3-5 are obtained by organic ligands bridging Pb(II) or Zn(II), leading to a new type of metal-organic coordination polymer.

References

Mar 23, 2001·Inorganic Chemistry·W HuangQ Meng
Aug 30, 2001·Acta Crystallographica. Section A, Foundations of Crystallography·V MocellaJ Härtwig
Jun 19, 1998·Angewandte Chemie·Stuart R Batten, Richard Robson
Feb 15, 1999·Angewandte Chemie·Kumar BiradhaMichael J Zaworotko

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Citations

Dec 20, 2007·Chemistry : a European Journal·Liwei MiYaoting Fan
Feb 25, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Vadapalli Chandrasekhar, Ramalingam Thirumoorthi
Jun 2, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Anne F RichardsConor F Hogan
Feb 2, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Qin-Yu ZhuJie Dai
Oct 10, 2008·The Journal of Organic Chemistry·Koushik GhoshPeter J Stang
Aug 6, 2019·ACS Applied Materials & Interfaces·Yin QinGang Li
Dec 30, 2010·Inorganic Chemistry·Balasubramanian Murugesapandian, Peter W Roesky
Jul 19, 2005·Inorganic Chemistry·Ming-Xue LiQing-Jin Meng

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