Self-Assembly of Chiral Metallacycles and Metallacages from a Directionally Adaptable BINOL-Derived Donor

Journal of the American Chemical Society
Yang YePeter J Stang

Abstract

We present the formation of a series of chiral metallacycles and metallacages by the use of a BINOL-derived dicarboxylate as a donor that is capable of affording a variety of coordination angles between its two Lewis basic sites. Two squares, two rhomboids, two tetragonal prisms, and one hexagonal prism were successfully formed when the chiral dicarboxylate donor self-assembled with one of four ditopic Pt(II) complexes, including two bimetallic 180° Pt-based acceptors, a 120° bimetallic Pt-based acceptor, and a 90° mononuclear Pt-based acceptor. Their structures were well characterized by (31)P{(1)H} NMR, ESI-MS, CD, and optical rotation analyses.

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Citations

Jan 16, 2016·Journal of the American Chemical Society·Bijnaneswar MondalPartha Sarathi Mukherjee
Oct 29, 2015·Journal of the American Chemical Society·Tanya K RonsonJonathan R Nitschke
May 10, 2016·Inorganic Chemistry·Xin WuJian Zhang
Sep 2, 2016·Journal of the American Chemical Society·Hai-Sen XuWei Wang
Jan 7, 2017·Journal of the American Chemical Society·Jinqiao DongYong Cui
Feb 6, 2017·Journal of the American Chemical Society·Hajar SepehrpourPeter J Stang
Oct 22, 2016·Chemistry : a European Journal·Ori GidronFrançois Diederich
Jun 3, 2016·Angewandte Chemie·Ana M CastillaMaarten M J Smulders
Sep 23, 2016·Angewandte Chemie·Ana M CastillaMaarten M J Smulders
Jun 27, 2017·Chemical Communications : Chem Comm·Yu WangXiaoyu Cao
Jan 26, 2017·Chemical Communications : Chem Comm·Ken Chi-Hang TsoChi-Ming Che
Mar 16, 2017·Chemical Communications : Chem Comm·Hong-Yu ChenJiao-Bing Wang
Jan 24, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Achintya JanaNeeladri Das
Aug 25, 2018·Macromolecular Rapid Communications·Yu-Xuan WangHai-Bo Yang
Sep 5, 2018·Chemical Society Reviews·Hai-Tao FengBen Zhong Tang
Jul 20, 2018·Chemistry : a European Journal·Bin SunJoost N H Reek
Feb 28, 2019·Chemical Communications : Chem Comm·Martha KohlhaasJochen Niemeyer
Apr 30, 2017·Chemical Society Reviews·Li-Jun ChenMitsuhiko Shionoya
Nov 20, 2016·Proceedings of the National Academy of Sciences of the United States of America·Guocan YuPeter J Stang
Jul 22, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Hannah SoudryHani Amouri
Dec 28, 2016·Journal of Materials Chemistry. B, Materials for Biology and Medicine·Jiong ZhouFeihe Huang
Jun 27, 2020·Chemistry : a European Journal·Jian-Gang YuYing-Feng Han
Dec 31, 2020·Journal of the American Chemical Society·Die LiuPingshan Wang
Jan 30, 2021·Angewandte Chemie·Xianhui TangYan Liu
Jun 15, 2021·Journal of the American Chemical Society·You-Quan ZouJonathan R Nitschke
May 21, 2020·Journal of the American Chemical Society·Tao HongPeter J Stang
May 22, 2020·Organic Letters·Doudou LiPeter J Stang
Mar 30, 2018·The Journal of Organic Chemistry·Nianqiang JiangJiaobing Wang
Aug 26, 2017·Journal of the American Chemical Society·Hang QuXiaoyu Cao
May 23, 2018·Journal of the American Chemical Society·Jiong ZhouTimothy R Cook
Oct 6, 2020·Journal of the American Chemical Society·Huangtianzhi ZhuPeter J Stang
Jul 23, 2019·Journal of the American Chemical Society·Ji-Young KimNicholas Kotov

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