Self-assembly of unprecedented [8+12] Cu-metallamacrocycle-based 3D metal-organic frameworks

Chemical Communications : Chem Comm
Zhouqing XuYaoting Fan

Abstract

[8+12]-metallamacrocycle-based 3D frameworks {[Cu(4)(pbt)(2)(SO(4))(2)(DMF)(2)(CH(3)OH)]·7H(2)O·DMF}(n) (1) and [12]-macrocycle 3D {[Cu(2)(pbt)(SO(4))(DMSO)(CH(3)OH)(2)]·5H(2)O·CH(3)OH}(n) (2) have been obtained. Both complexes display antiferromagnetic couplings and high catalytic activity in the oxidative coupling reaction of 1-ethynylbenzene and oxazolidin-2-one.

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Citations

Nov 21, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Yun DuYao-Yu Wang
Jan 23, 2015·Chemical Society Reviews·Amarajothi DhakshinamoorthyHermenegildo Garcia
Dec 18, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Lei-Lei LiuLu-Fang Ma
Oct 22, 2019·Chemical Communications : Chem Comm·Zhichao ShaoHongwei Hou
Nov 22, 2014·Chemistry : a European Journal·M Jesús PastorLuis Sánchez

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