Semimetal-functionalised polyoxovanadates

Chemical Society Reviews
Kirill Yu MonakhovPaul Kögerler

Abstract

Polyoxovanadates (POVs), known for their wide applicability and relevance in chemical, physical and biological sciences, are a subclass of polyoxometalates and usually self-assemble in aqueous-phase, pH-controlled condensation reactions. Archetypical POVs such as the robust [VO42](12-) polyoxoanion can be structurally, electronically and magnetically altered by heavier group 14 and 15 elements to afford Si-, Ge-, As- or Sb-decorated POV structures (heteroPOVs). These main-group semimetals introduce specific chemically engineered functionalities which cause the generally hydrophilic heteroPOV compounds to exhibit interesting reactivity towards organic molecules, late transition metal and lanthanoid ions. The fully-oxidised (V(V)), mixed-valent (V(V)/V(IV) and V(IV)/V(III)), "fully-reduced" (V(IV)) and "highly-reduced" (V(III)) heteroPOVs possess a number of intriguing properties, ranging from catalytic to molecular magnet characteristics. Herein, we review key developments in the synthetic and structural chemistry as well as the reactivity of POVs functionalised with Si-, Ge-, As- or Sb-based heterogroups.

References

Jul 1, 1977·Journal of Molecular Biology·E F PaiG E Schulz
Mar 1, 1985·Biochimica Et Biophysica Acta·D W BoydM Niwa
Sep 15, 1985·The Biochemical Journal·P CsermelyA J Ejchart
Jun 12, 1981·Biochimica Et Biophysica Acta·H U Meisch, L J Becker
Jan 5, 2002·Journal of the American Chemical Society·Elizabeth E HamiltonJonathan J Wilker
Apr 2, 2002·Inorganic Chemistry·Adam J Bridgeman, Germán Cavigliasso
Oct 29, 2002·Inorganic Chemistry·Reto BaslerHans-Ulrich Güdel
Jun 10, 2003·Inorganic Chemistry·T WhitfieldA J Jacobson
Aug 28, 2003·Journal of the American Chemical Society·Akhilesh TripathiAbraham Clearfield
Mar 24, 2004·Angewandte Chemie·Robert Schlögl, Sharifah Bee Abd Hamid
Nov 26, 2004·Journal of the American Chemical Society·Athanasios B BourlinosEmmanuel P Giannelis
Jun 16, 2005·Journal of the American Chemical Society·Lian ChenMaochun Hong
Aug 11, 2005·Journal of the American Chemical Society·Yun Hang Hu, Eli Ruckenstein
Sep 22, 2005·Chemical Communications : Chem Comm·M Ishaque KhanCharles J O'Connor
Oct 20, 2005·Journal of the American Chemical Society·Michio YamadaShigeru Nagase
Nov 17, 2005·Journal of the American Chemical Society·Zhongxin GeHarry C Dorn
Nov 18, 2005·Chemical Communications : Chem Comm·Bogdan BotarCraig L Hill
Jan 21, 2006·Angewandte Chemie·Dragan PitzschkeWolfgang Bensch
Feb 24, 2006·The Journal of Physical Chemistry. a·Sandra FeyelHelmut Schwarz
Jun 17, 2006·Chemical Communications : Chem Comm·Ian S TidmarshEric J L McInnes
Jan 18, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Paul G RickertMark L Dietz
Mar 14, 2007·Journal of Inorganic Biochemistry·S S SoaresM Aureliano
May 4, 2007·The Journal of Physical Chemistry. B·Paul G RickertMark L Dietz
May 23, 2007·Chemistry : a European Journal·Ian S TidmarshEric J L McInnes

❮ Previous
Next ❯

Citations

Oct 27, 2015·Inorganic Chemistry·Weiwei GuoCraig L Hill
Jul 21, 2016·Inorganic Chemistry·Feng LiEllen M Matson
Aug 16, 2016·Inorganic Chemistry·Yuteng ZhangZhongmin Su
May 26, 2017·Inorganic Chemistry·Maren RasmussenWolfgang Bensch
Jan 14, 2017·Chemistry : a European Journal·Aleksandar Kondinski, Kirill Yu Monakhov
Jan 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·M WendtW Bensch
Apr 23, 2017·Chemistry, an Asian Journal·Sho KuwajimaYoshihito Hayashi
Jan 5, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Yang-Yang HuJi-Qing Xu
Jan 11, 2018·Chemistry : a European Journal·Maria NicolaouHaralampos N Miras
Apr 25, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·M WendtW Bensch
Sep 30, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Oliver LinnenbergKirill Yu Monakhov
Jun 17, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Maren RasmussenWolfgang Bensch
Oct 19, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Sebastian SchmitzKirill Yu Monakhov
Oct 7, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Yu-Teng ZhangZhong-Min Su
Nov 1, 2017·Physical Chemistry Chemical Physics : PCCP·Piotr KozłowskiKirill Yu Monakhov
Aug 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Oliver LinnenbergKirill Yu Monakhov
Oct 12, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Chao ChenEn-Bo Wang
Mar 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Haijiao LuSebastian D Pike
Apr 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuji KikukawaYoshihito Hayashi
Jan 13, 2018·Angewandte Chemie·Lisa K MahnkeWolfgang Bensch
Dec 4, 2019·Chemical Society Reviews·Alexander V AnyushinTatjana N Parac-Vogt
Jan 28, 2020·Chemistry : a European Journal·Jing Yang NiuJingping Wang
Aug 25, 2020·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Sergey V Krivovichev
May 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sateesh MulkapuriSamar K Das
Mar 27, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Youyou YuanJunliang Sun
May 14, 2020·Advanced Biosystems·Kun ChenYongge Wei
Apr 21, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Michela L MaiolaEllen M Matson
May 26, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·William SalomonAnne Dolbecq
Jun 18, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Hai-Yang GuoXiao-Bing Cui
Jan 16, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Xing LiuLianshe Fu
Sep 25, 2020·Chemical Communications : Chem Comm·Dongdi ZhangTianbo Liu
Feb 19, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Pradip Kumar SahuSanjit Konar

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.