Abstract
Carbon dioxide is the main undesirable compound present in raw natural gas and biogas. Physisorption based adsorption processes such as pressure swing adsorption (PSA) are one of the solutions to selectively adsorb CO(2) from CH(4). Some hybrid crystalline porous materials that belong to the family of metal-organic frameworks (MOFs) show larger CO(2) adsorption capacity compared to the usual industrial adsorbents, such as zeolites and most activated carbons, which makes them potentially promising for such applications. However, their selectivity values have been most often determined using only single gas adsorption measurements combined with simple macroscopic thermodynamic models or by means of molecular simulations based on generic forcefields. The transfer of this systematic approach to all MOFs, whatever their complex physico-chemical features, needs to be considered with caution. In contrast, direct co-adsorption measurements collected on these new materials are still scarce. The aim of this study is to perform a complete analysis of the CO(2)-CH(4) co-adsorption in the mesoporous MIL-100(Cr) MOF (MIL stands for Materials from Institut Lavoisier) by means of a synergic combination of outstanding experimental and modelling...Continue Reading
References
Sep 17, 2004·Angewandte Chemie·Gérard FéreyIrène Margiolaki
Mar 9, 2006·Journal of the American Chemical Society·Alexandre VimontNathalie Audebrand
Nov 16, 2006·Journal of the American Chemical Society·Suzy SurbléGérard Férey
Mar 22, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Philip L LlewellynGérard Férey
Jul 10, 2008·Langmuir : the ACS Journal of Surfaces and Colloids·Martin HartmannAlex Wagener
Aug 7, 2008·Inorganic Chemistry·Sebastian BauerNorbert Stock
Sep 20, 2008·Chemical Communications : Chem Comm·Antje HenschelStefan Kaskel
May 15, 2009·Journal of the American Chemical Society·Mainak BanerjeeKimoon Kim
Jun 10, 2009·Journal of the American Chemical Society·Lomig HamonGuy De Weireld
Aug 8, 2009·Chemical Communications : Chem Comm·Jun KimWha-Seung Ahn
Oct 8, 2009·Journal of the American Chemical Society·Kathryn M L Taylor-PashowWenbin Lin
Nov 13, 2009·Journal of the American Chemical Society·Lomig HamonGérard Férey
Nov 19, 2009·Chemical Communications : Chem Comm·Aude DemessenceGérard Férey
Dec 22, 2009·Chemical Communications : Chem Comm·Shengqian Ma, Hong-Cai Zhou
Jan 22, 2010·Angewandte Chemie·Zhi-Yuan Gu, Xiu-Ping Yan
Jan 28, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Y F ChenJ W Jiang
Feb 11, 2010·Environmental Science & Technology·Dipendu SahaShuguang Deng
Feb 20, 2010·Inorganic Chemistry·Nataliya V MaksimchukOxana A Kholdeeva
Jul 3, 2010·Science·Hiroyasu FurukawaOmar M Yaghi
Dec 25, 2010·Chemical Society Reviews·Gérard FéreyJong-San Chang
May 20, 2011·Chemical Communications : Chem Comm·Joaquín Silvestre-AlberoFrancisco Rodríguez-Reinoso
Jul 30, 2011·Chemical Communications : Chem Comm·Qingyuan YangGuillaume Maurin
Citations
Jul 6, 2013·Chemical Reviews·Qingyuan YangJian-Rong Li
Oct 10, 2014·The Journal of Chemical Physics·Thuat T TrinhSigne Kjelstrup
Dec 18, 2013·Environmental Science and Pollution Research International·Rana SabouniSohrab Rohani
Feb 7, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Andrew D WiersumPhilip L Llewellyn
Aug 4, 2018·Small·Dingxin LiuJianyong Zhang
Nov 8, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Anupam Khutia, Christoph Janiak
Mar 14, 2020·Chemical Communications : Chem Comm·Rijia LinVicki Chen
Jul 29, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Nian ZhaoHongming He
Jun 22, 2013·Angewandte Chemie·Qingyuan YangGuillaume Maurin
Jan 31, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Shyam BiswasPascal Van Der Voort
Jan 25, 2020·Langmuir : the ACS Journal of Surfaces and Colloids·Praveen Bollini, Jacklyn Hall
Jul 25, 2019·ACS Applied Materials & Interfaces·Mayank Agrawal, David S Sholl
Mar 14, 2018·Langmuir : the ACS Journal of Surfaces and Colloids·Yen-Ru ChenLi-Chiang Lin
Jan 30, 2018·Inorganic Chemistry·Miroslav AlmášiJiří Čejka
Nov 18, 2015·Journal of Chemical Theory and Computation·Lukáš GrajciarMiroslav Rubeš
Nov 10, 2020·ACS Omega·Maha Alhaddad, Sheta M Sheta
Oct 16, 2021·Inorganic Chemistry·Timothy SteenhautSophie Hermans