Seven Coordinated Molecular Ruthenium-Water Oxidation Catalysts: A Coordination Chemistry Journey

Chemical Reviews
Roc MatheuAntoni Llobet

Abstract

Molecular water oxidation catalysis is a field that has experienced an impressive development over the past decade mainly fueled by the promise of generation of a sustainable carbon neutral fuel society, based on water splitting. Most of these advancements have been possible thanks to the detailed understanding of the reactions and intermediates involved in the catalytic cycles. Today's best molecular water oxidation catalysts reach turnover frequencies that are orders of magnitude higher than that of the natural oxygen evolving center in photosystem II. These catalysts are based on Ru complexes where at some stage, the first coordination sphere of the metal center becomes seven coordinated. The key for this achievement is largely based on the use of adaptative ligands that adjust their coordination mode depending on the structural and electronic demands of the metal center at different oxidation states accessed within the catalytic cycle. This Review covers the latest and most significant developments on Ru complexes that behave as powerful water oxidation catalysts and where at some stage the Ru metal attains coordination number 7. Further it provides a comprehensive and rational understanding of the different structural and ...Continue Reading

References

Nov 17, 2001·Chemical Reviews·B M TrostA B Pinkerton
Jan 5, 2002·Journal of the American Chemical Society·Christian R GoldsmithT Daniel P Stack
Jun 26, 2002·Biochemistry·Fabrice RappaportJérôme Lavergne
Nov 7, 2002·Journal of the American Chemical Society·Dimitri OssipovJyoti Chattopadhyaya
Jun 24, 2004·Journal of the American Chemical Society·Cristina SensJordi Benet-Buchholz
Jun 9, 2005·Chemical Reviews·Lothar Helm, André E Merbach
Oct 18, 2006·Proceedings of the National Academy of Sciences of the United States of America·Nathan S Lewis, Daniel G Nocera
Sep 30, 2009·Chemical Reviews·Michael P DoyleLei Zhou
Oct 2, 2009·Journal of the American Chemical Society·Fernando BozoglianAntoni Llobet
Nov 17, 2009·Accounts of Chemical Research·Sophie RomainAntoni Llobet
Jan 21, 2010·Journal of the American Chemical Society·Javier J ConcepcionThomas J Meyer
Aug 12, 2010·Journal of the American Chemical Society·W Chadwick EllisTerrence J Collins
Sep 25, 2010·Angewandte Chemie·Takahiko KojimaShunichi Fukuzumi
Oct 12, 2010·Chemical Reviews·Jeffrey J WarrenJames M Mayer
Oct 28, 2010·Accounts of Chemical Research·James M Mayer
Mar 2, 2011·Chemical Communications : Chem Comm·Derek J WasylenkoCurtis P Berlinguette
Oct 18, 2011·Inorganic Chemistry·Bhasker RadaramXuan Zhao
Jun 19, 2012·Chemical Reviews·David R WeinbergThomas J Meyer
Sep 1, 2012·Chemical Reviews·Percia Beatrice ArockiamPierre H Dixneuf
Sep 19, 2012·Proceedings of the National Academy of Sciences of the United States of America·André KlaussHolger Dau
Oct 9, 2012·Science·Cyrille CostentinJean-Michel Savéant
Feb 16, 2013·Inorganic Chemistry·Lianpeng TongLicheng Sun
Mar 8, 2013·Journal of the American Chemical Society·Yan GaoLicheng Sun
Mar 20, 2013·Accounts of Chemical Research·Nicholas CoxWolfgang Lubitz
Jul 5, 2013·Journal of the American Chemical Society·Ulrich HintermairRobert H Crabtree
Sep 6, 2013·Nature·John S AndersonJonas C Peters
Dec 18, 2013·Accounts of Chemical Research·Xavier SalaAntoni Llobet
Jan 30, 2014·Chemical Society Reviews·Serena BerardiAntoni Llobet
Oct 29, 2014·Angewandte Chemie·Hong-Yan WangAnders Thapper
Oct 30, 2014·Chemical Reviews·Markus D KärkäsBjörn Åkermark
Nov 8, 2014·Chemistry : a European Journal·Craig J RichmondAntoni Llobet
Nov 20, 2014·Journal of the American Chemical Society·Andrew M UllmanDaniel G Nocera

❮ Previous
Next ❯

Citations

Nov 26, 2019·Advanced Materials·Douglas R MacFarlaneAlexandr N Simonov
Feb 25, 2020·Physical Chemistry Chemical Physics : PCCP·Yuting LiuLikai Yan
Jun 20, 2020·Angewandte Chemie·Julien Warnan, Erwin Reisner
Oct 1, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Timofey LiseevSascha Ott
Jun 22, 2019·Proceedings of the National Academy of Sciences of the United States of America·Degao Wang, Thomas J Meyer
Oct 21, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jesús A Luque-UrrutiaAlbert Poater
Nov 27, 2020·Chemistry : a European Journal·Niklas Noll, Frank Würthner
Dec 18, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Tarali DeviWonwoo Nam
Feb 6, 2021·Journal of Biological Inorganic Chemistry : JBIC : a Publication of the Society of Biological Inorganic Chemistry·Jinmiao WangMei Wang
Feb 9, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Guo ChenXiao-Yi Yi
Nov 24, 2020·Chemical Science·Pascal FriederichDavid Balcells
Dec 15, 2020·Chemical Society Reviews·Shunichi FukuzumiWonwoo Nam
Mar 27, 2021·Angewandte Chemie·Mingtian ZhangRongzhen Liao
Jun 18, 2021·Inorganic Chemistry·Samir ChattopadhyayAbhishek Dey
Jul 23, 2021·Journal of the American Chemical Society·Marcos Gil-SepulcreAntoni Llobet
Jan 4, 2020·Chemical Reviews·M Rosa Axet, Karine Philippot
Apr 22, 2020·Inorganic Chemistry·Mehmed Z Ertem, Javier J Concepcion
Jul 10, 2019·The Journal of Physical Chemistry. a·Paul A Davethu, Sam P de Visser
Aug 14, 2020·The Journal of Physical Chemistry Letters·Juan Angel de Gracia Triviño, Mårten S G Ahlquist
Mar 11, 2020·Inorganic Chemistry·Abolfazl GhaderianCarolina Gimbert-Suriñach
Dec 24, 2019·Journal of the American Chemical Society·Alireza Karbakhsh RavariYulia Pushkar
Oct 12, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Sinval F SousaAntonio Otavio T Patrocinio
Jan 7, 2022·Journal of the American Chemical Society·Young Hyun HongShunichi Fukuzumi

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.