Silicon-induced phenanthrene formation from benzynes and allenylsilanes

Chemistry : a European Journal
Jih Ru Hwu, Sharada P Swain

Abstract

Now directly feasible: The silicon atom in allenylsilanes enabled their reaction with two equivalents of benzynes to generate (α-phenanthrenyl)vinylsilanes in good to excellent yields through an unprecedented [2+2+2] pathway (see scheme).

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Citations

Oct 21, 2015·Chemistry : a European Journal·Venkata R SabbasaniDaesung Lee
Feb 19, 2021·Chemical Reviews·Jiarong ShiYang Li
Jul 4, 2020·The Journal of Organic Chemistry·Jih Ru HwuShwu-Chen Tsay

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