Silver-guided excimer emission in an adenine-pyrene conjugate: fluorescence lifetime and crystal studies

Inorganic Chemistry
Mrituanjay D PandeySandeep Verma

Abstract

This Communication describes a novel adenine-pyrene conjugate (1) and its solid-state structure with silver and copper ions. Single-crystal studies of metal complexes of 1 offer insight into molecular interactions and provide a basis to rationalize possible interactions in the solution state, leading to excimer formation. The robust nature of this interaction was further confirmed by deposition of the silver complex on a graphite surface, which exhibited a remarkable resemblance to its solid-state structure. The structural basis of selective excimer formation in the presence of Ag(+) ions presents a viable approach for ratiometric detection of these ions.

References

Nov 18, 2000·Analytical Chemistry·K KimuraM Oue
Sep 30, 2005·Nature·Johannes V BarthKlaus Kern
Jan 13, 2006·Journal of the American Chemical Society·Chandra Shekhar Purohit, Sandeep Verma
Oct 24, 2006·Chemical Society Reviews·Mario RubenPaul Müller
Mar 7, 2007·Journal of the American Chemical Society·Chandra Shekhar Purohit, Sandeep Verma
Sep 15, 2007·Inorganic Chemistry·Chandra Shekhar PurohitSandeep Verma
Sep 18, 2007·Environmental Toxicology and Chemistry·Mariana Saia PedrosoAdalto Bianchini
Feb 19, 2008·Nature Chemical Biology·Dylan W DomailleChristopher J Chang
Mar 5, 2009·Chemical Communications : Chem Comm·Cong Yu, Vivian Wing-Wah Yam
Jun 19, 2009·Inorganic Chemistry·Jitendra Kumar, Sandeep Verma
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Sep 3, 2009·Organic Letters·Ruixing ZhangVivian W W Yam
Sep 24, 2009·Chemical Reviews·Reagan McRaeChristoph J Fahrni

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Citations

Mar 23, 2011·Inorganic Chemistry·Rajneesh Kumar Prajapati, Sandeep Verma
Jun 28, 2016·Inorganic Chemistry·Soham MandalJens Müller
Apr 11, 2017·Chemical Communications : Chem Comm·Balaram MohapatraSandeep Verma
Feb 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Zheng-Yu LiuXiao-Jun Zhao
Apr 11, 2018·Methods and Applications in Fluorescence·Ming Jun CenYong Wu He
Aug 26, 2017·Journal of Fluorescence·Manzoor Ahmad WaniDebabrata Goswami
Apr 21, 2012·Chemistry : a European Journal·Ritesh HaldarTapas Kumar Maji
Sep 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·En-Cui YangXiao-Jun Zhao
Oct 1, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Ashutosh Kumar MishraSandeep Verma
Dec 18, 2010·Chemical Communications : Chem Comm·Shanshan HuangLiancheng Zhao
Sep 26, 2012·Acta Crystallographica. Section C, Crystal Structure Communications·Jian Long DuPei Li
Nov 27, 2010·Chemical Communications : Chem Comm·N Nagapradeep, Sandeep Verma
Nov 16, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·N NagapradeepSandeep Verma
Mar 27, 2010·Inorganic Chemistry·Ashutosh Kumar Mishra, Sandeep Verma
Aug 11, 2010·Inorganic Chemistry·Ashutosh Kumar Mishra, Sandeep Verma

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