Simultaneous construction of two linkages for the on-surface synthesis of imine-boroxine hybrid covalent organic frameworks

Chemical Science
Jie-Yu YueDong Wang

Abstract

The orthogonality between the Schiff base reaction and the boronic acid dehydration reaction is explored during the on-surface synthesis process. By activating the above two reactions in one-step and employing asymmetrical substituted monomers and the 3-fold symmetric monomer 1,3,5-tris(4-aminophenyl)benzene (TAPB), highly ordered imine-boroxine hybrid single-layered covalent organic frameworks (sCOFs) have been successfully constructed on HOPG by a gas-solid interface reaction method and characterized by scanning tunnelling microscopy (STM). In particular, the reaction between the meta-substituted monomer and TAPB generates sCOFB with a windmill structure, which is the first sCOF with surface chirality so far reported. The demonstration of the one-step synthesis of multiple linkages to form sCOFs can further enlarge the sCOF family and expand the design routes for functional 2D organic nanomaterials.

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Citations

Dec 29, 2017·Nanomaterials·Fuli ZhaoJianhua Zhang
Jun 13, 2019·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Lili CaoShengbin Lei
Oct 28, 2019·Chemical Communications : Chem Comm·Daling CuiSylvain Clair
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May 6, 2020·Chemical Society Reviews·Jie LiBo Wang
Jul 1, 2020·Chemical Society Reviews·Yinghua JinWei Zhang
May 19, 2020·Chemical Society Reviews·Han WangJunwang Tang
May 8, 2020·Chemical Society Reviews·Yusen LiLong Chen
Apr 28, 2021·Organic Letters·Wojciech DrożdżArtur R Stefankiewicz
Jul 12, 2017·ACS Central Science·Ryan P Bisbey, William R Dichtel
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Feb 6, 2020·ACS Nano·Nerea BilbaoSteven De Feyter
Apr 20, 2019·Langmuir : the ACS Journal of Surfaces and Colloids·Li-Mei WangDong Wang
Dec 2, 2021·Chemical Reviews·Austin M EvansWilliam R Dichtel

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Methods Mentioned

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