Single-molecule magnet behavior in luminescent carbazolyl Dy(iii) octahedral complexes with a quasi linear N- -Dy-N- angle

Dalton Transactions : an International Journal of Inorganic Chemistry
Jérôme LongAlexander A Trifonov

Abstract

We report the synthesis, photoluminescence and magnetic properties of two octahedral dysprosium complexes [DyR2(py)4][BPh4]·2py (1) and [DyR2(THF)4][BPh4] (2) (R = carbazolyl, py = pyridine, THF = tetrahydrofuran) exhibiting a quasi linear N-Dy-N angle in the axial direction, suitable for providing a coordination environment allowing the zero-field slow relaxation of magnetization.

References

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Citations

Dec 22, 2020·Chemical Communications : Chem Comm·Lewis R Thomas-HargreavesStephen T Liddle
Oct 1, 2020·Chemistry : a European Journal·Xia-Li DingYan-Zhen Zheng
Apr 4, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Uwe BayerReiner Anwander
May 29, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Jérôme LongAlexander A Trifonov

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