Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

Journal of the American Chemical Society
Shang-Zheng SunRuben Martin

Abstract

A mild, chemo- and site-selective catalytic protocol that allows for incorporating an alkylboron fragment into unactivated olefins is described. The use of internal olefins enables C-C bond-formation at remote sp3 C-H sites, constituting a complementary and conceptually different approach to existing borylation techniques that are currently available at sp3 centers.

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Citations

May 6, 2019·Angewandte Chemie·Yangyang LiGuoyin Yin
May 11, 2019·Chemistry : a European Journal·Basudev SahooRuben Martin
Oct 24, 2019·Angewandte Chemie·Deyun Qian, Xile Hu
Dec 5, 2019·Angewandte Chemie·Jie LiWanxiang Zhao
Jan 8, 2020·Angewandte Chemie·Shang-Zheng SunRuben Martin
Feb 6, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Chenkai MengJun Yi
Apr 17, 2019·Nature Communications·Yulong ZhangShaolin Zhu
Oct 13, 2020·European Journal of Organic Chemistry·Gabriel J Lovinger, James P Morken
Dec 1, 2020·Angewandte Chemie·Hong-Gang ChengQianghui Zhou
Jan 23, 2021·Journal of the American Chemical Society·Deyun QianXile Hu
Jan 29, 2021·Nature Communications·Yuli HeShaolin Zhu
May 16, 2020·Journal of the American Chemical Society·Sean P RossMatthew S Sigman
Nov 24, 2020·Organic Letters·Chenchen WangYifeng Chen
Sep 26, 2019·Organic Letters·John M Lopp, Valerie A Schmidt
Oct 8, 2019·Journal of the American Chemical Society·Qiao Lin, Tianning Diao
Apr 30, 2019·Journal of the American Chemical Society·Samantha A GreenRyan A Shenvi
Mar 30, 2019·Organic Letters·Raul Martin-MonteroRuben Martin
Aug 26, 2021·Organic Letters·Krishnamoorthy MuralirajanMagnus Rueping
Aug 1, 2019·Journal of the American Chemical Society·Rong-De HeXing-Zhong Shu
Aug 27, 2021·Journal of the American Chemical Society·Jian Chen, Shaolin Zhu
Oct 1, 2019·Journal of the American Chemical Society·Shang-Zheng SunRuben Martin

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