Sodium hypochlorite as an alternative to hydrogen peroxide in Fenton process for industrial scale

Water Research
Jamshid BehinMehdi Khajeh

Abstract

In present work, the treatment of aromatic compounds of simulated wastewater was performed by Fenton and NaOCl/Fe(2+) processes. The model solution was prepared based on the wastewater composition of Diisocyanate unit of Karoon Petrochemical Company/Iran containing Diamino-toluenes, Nitro-phenol, Mononitro-toluene, Nitro-cresol, and Dinitro-toluene. Experiments were conducted in a batch mode to examine the effects of operating variables such as pH, oxidant dosages, ferrous ion concentration and numbers of feeding on COD removal. Taguchi experimental design was used to determine the optimum conditions. The COD removal efficiency under optimum conditions (suggested by Taguchi design) in Fenton and NaOCl/Fe(2+) processes was 88.7% and 83.4%, respectively. The highest contribution factor in Fenton process belongs to pH (47.47%) and in NaOCl/Fe(2+) process belongs to NaOCl/pollutants (50.26%). High regression coefficient (R(2): 0.98) obtained for Taguchi method, indicates that models are statistically significant and are in well agreement with each other. The NaOCl/Fe(2+) process utilizing a conventional oxidant, in comparison to hydrogen peroxide, is an efficient cost effective process for COD removal from real wastewater, although...Continue Reading

Citations

Jul 30, 2018·Environmental Science and Pollution Research International·Xiaofei ZhuDongbo Wang
Oct 9, 2020·Water Science and Technology : a Journal of the International Association on Water Pollution Research·Wenying Xu, Haoyang Gao
Aug 18, 2021·Journal of Environmental Science and Health. Part A, Toxic/hazardous Substances & Environmental Engineering·Rayany Magali da Rocha SantanaMarta Maria Menezes Bezerra Duarte

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