Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal-organic frameworks.

Chemical Science
Eike Brunner, Marcus Rauche

Abstract

Metal-organic frameworks (MOFs) gain increasing interest due to their outstanding properties like extremely high porosity, structural variability, and various possibilities for functionalization. Their overall structure is usually determined by diffraction techniques. However, diffraction is often not sensitive for subtle local structural changes and ordering effects as well as dynamics and flexibility effects. Solid-state nuclear magnetic resonance (ssNMR) spectroscopy is sensitive for short range interactions and thus complementary to diffraction techniques. Novel methodical advances make ssNMR experiments increasingly suitable to tackle the above mentioned problems and challenges. NMR spectroscopy also allows study of host-guest interactions between the MOF lattice and adsorbed guest species. Understanding the underlying mechanisms and interactions is particularly important with respect to applications such as gas and liquid separation processes, gas storage, and others. Special in situ NMR experiments allow investigation of properties and functions of MOFs under controlled and application-relevant conditions. The present minireview explains the potential of various solid-state and in situ NMR techniques and illustrates thei...Continue Reading

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Citations

Sep 10, 2020·Advanced Materials·Shenhui LiFeng Deng
Jun 25, 2021·Chemical Science·Sharon E AshbrookCameron M Rice
Jun 8, 2021·Chemical Science·Aaron Torres-HuertaBraulio Rodríguez-Molina
Jan 15, 2021·Physical Chemistry Chemical Physics : PCCP·Diego CarnevaleDaniel Abergel
Jan 7, 2021·ACS Applied Materials & Interfaces·Tomislav StolarKrunoslav Užarević
Sep 7, 2021·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Patrick Melix, Thomas Heine

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Methods Mentioned

BETA
NMR
nuclear magnetic resonance
X-ray
ssNMR
2D

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