Solvent-free ball-milling subcomponent synthesis of metallosupramolecular complexes

Chemistry : a European Journal
Chandan GiriPrasenjit Mal

Abstract

Subcomponent self-assembly from components A, B, C, D, and Fe(2+) under solvent-free conditions by self-sorting leads to the construction of three structurally different metallosupramolecular iron(II) complexes. Under carefully selected ball-milling conditions, tetranuclear [Fe4 (AD2 )6 ](4-) 22-component cage 1, dinuclear [Fe2 (BD2 )3 ](2-) 11-component helicate 2, and 5-component mononuclear [Fe(CD3 )](2+) complex 3 were prepared simultaneously in a one-pot reaction from 38 components. Through subcomponent substitution reaction by adding subcomponent B, the [Fe4 (AD2 )6 ](4-) cage converts quantitatively to the [Fe2 (BD2 )3 ](2-) helicate, which, in turn, upon addition of subcomponent C, transforms to [Fe(CD3 )](2+) , following the hierarchical preference based on the thermodynamic stability of the complexes.

References

Feb 9, 2005·Chemical Communications : Chem Comm·Jochen AntesbergerJerry L Atwood
Nov 30, 2006·Angewandte Chemie·Euan R KayFrancesco Zerbetto
Jan 17, 2008·Chemical Society Reviews·R Frederick Ludlow, Sijbren Otto
Aug 30, 2008·Angewandte Chemie·Prasenjit MalJonathan R Nitschke
Jun 27, 2009·Science·Prasenjit MalJonathan R Nitschke
Dec 17, 2009·Nature·Jonathan R Nitschke
Apr 10, 2010·Chemical Communications : Chem Comm·Prasenjit Mal, Jonathan R Nitschke
Mar 10, 2011·Chemical Society Reviews·Achim StolleBernd Ondruschka
Jul 19, 2011·Angewandte Chemie·Karolina Osowska, Ognjen Š Miljanić
Aug 19, 2011·Chemical Reviews·Marina M Safont-SempereFrank Würthner
Aug 26, 2011·Chemical Reviews·Rajesh ChakrabartyPeter J Stang
Sep 6, 2011·Chemical Society Reviews·Stuart L JamesDaniel C Waddell
Oct 7, 2011·Journal of the American Chemical Society·Yao-Rong ZhengPeter J Stang
Feb 9, 2012·Chemical Society Reviews·Matthew E Belowich, J Fraser Stoddart
Apr 27, 2012·Accounts of Chemical Research·Nicolas Giuseppone
May 1, 2012·Organic & Biomolecular Chemistry·Manik Lal Saha, Michael Schmittel
Aug 15, 2012·Chemical Society Reviews·Jean-François AymeDavid A Leigh
Oct 4, 2012·Chemical Society Reviews·Maarten M J SmuldersJonathan R Nitschke
Dec 19, 2012·Nature Chemistry·Tomislav FriščićRobert E Dinnebier
Dec 28, 2012·Journal of the American Chemical Society·Koushik AcharyyaPartha Sarathi Mukherjee
Jan 12, 2013·Science·Bartosz LewandowskiDavid A Leigh
Jan 17, 2013·Chemical Society Reviews·Giancarlo CravottoPedro Cintas
Jan 25, 2013·Chemistry : a European Journal·Tanya K RonsonJonathan R Nitschke
Mar 21, 2013·Nature Chemistry·Tamoghna MitraAndrew I Cooper
Apr 4, 2013·Chemical Society Reviews·Dario BragaFabrizia Grepioni
Apr 6, 2013·Chemical Society Reviews·Peter BalážKrystyna Wieczorek-Ciurowa
Jun 7, 2013·Angewandte Chemie·Carmen TalottaPlacido Neri
Sep 17, 2013·Chemistry : a European Journal·Hana BunzenErkki Kolehmainen
Oct 15, 2013·Journal of the American Chemical Society·Xiao-Ping ZhouDan Li
Nov 1, 2013·Chemical Reviews·Kepa Ruiz-MirazoAndrés de la Escosura
Jan 23, 2014·Chemical Communications : Chem Comm·Soumen K SamantaMichael Schmittel
Jan 29, 2014·Chemical Communications : Chem Comm·Sandip Mukherjee, Partha Sarathi Mukherjee
Apr 1, 2014·Chemical Society Reviews·Jenny BrinkmannPascal Jonkheijm
May 6, 2014·Accounts of Chemical Research·Ana M CastillaJonathan R Nitschke
May 27, 2014·Journal of the American Chemical Society·Derrick A RobertsJonathan R Nitschke
Sep 17, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Chandan GiriKari Rissanen
Oct 23, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Chandan GiriKari Rissanen
Jan 15, 2015·Chemistry : a European Journal·Peter D FrischmannFrank Würthner

❮ Previous
Next ❯

Citations

Apr 26, 2019·Beilstein Journal of Organic Chemistry·Anima Bose, Prasenjit Mal
Oct 25, 2017·Beilstein Journal of Organic Chemistry·Tapas Kumar AcharPrasenjit Mal
May 8, 2018·Chemical Science·Marco LeonardiJ Carlos Menéndez
Sep 3, 2020·Chemical Science·Benjamin D EglestonRebecca L Greenaway
Aug 17, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ngoc Minh Tran, Hyojong Yoo
Apr 21, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Shigehisa Akine
May 7, 2019·Chemical Reviews·Audrey BeillardFrédéric Lamaty
Dec 10, 2016·Inorganic Chemistry·Manik Lal Saha, Michael Schmittel
Oct 24, 2017·Journal of the American Chemical Society·Amine GarciHanadi Sleiman

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.