Solvent-free synthesis of new inorganic-organic hybrid solids with finely tuned manganese oxalate structures

Dalton Transactions : an International Journal of Inorganic Chemistry
Lindong LuanHui Huang

Abstract

Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine molecules play a novel structure-directing role for the formation of different metal-organic skeletons within a specific framework topology.

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