Spin canting in the 3D anionic dicyanamide structure (SPh(3))Mn(dca)(3) (Ph = phenyl, dca = dicyanamide)

Inorganic Chemistry
John A SchlueterUrs Geiser

Abstract

Through use of the SPh(3)(+) (Ph = phenyl, C(6)H(5)) cation as a molecular template, a new three-dimensional Mn(dca)(3)(-) [dca = dicyanamide, N(CN)(2)(-)] anionic structure has been crystallized. At room temperature, (SPh(3))Mn(dca)(3) (1) crystallizes in the monoclinic space group P2(1)/c, with a = 11.7079(5) A, b = 12.8554(5) A, c = 16.8605(6) A, beta = 100.666(2) degrees, and V = 2493.8(3) A(3). Magnetic susceptibility measurements indicate that this salt exhibits a spin canted long range antiferromagnetically ordered ground state below 2.5 K.

Citations

Aug 11, 2005·Chemical Communications : Chem Comm·Young Sin YouChang Seop Hong
Dec 24, 2004·Dalton Transactions : an International Journal of Inorganic Chemistry·Patricia M Van der WerffKeith S Murray
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Nov 15, 2016·Physical Chemistry Chemical Physics : PCCP·Hanna L B BoströmAndrew L Goodwin
Dec 1, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Su-Yun ZhangZhang-Zhen He
May 16, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Hyun Hee KoChang Seop Hong
Sep 21, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhong-Yi LiuXiao-Jun Zhao
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Mar 16, 2006·Journal of the American Chemical Society·Hitoshi MiyasakaRodolphe Clérac

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