Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis

Chirality
Tsuneomi KawasakiKenso Soai

Abstract

An enantiomerically enriched pyrimidyl alkanol with either S or R configurations was obtained stochastically from the reaction between pyrimidine-5-carbaldehyde and diisopropylzinc in the presence of achiral silica gel in conjunction with asymmetric autocatalysis with amplification of chirality.

References

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Citations

Jun 4, 2008·Origins of Life and Evolution of the Biosphere : the Journal of the International Society for the Study of the Origin of Life·Béla BarabásGyula Pályi
Dec 17, 2010·Origins of Life and Evolution of the Biosphere : the Journal of the International Society for the Study of the Origin of Life·Francesco Faglioni, Inmaculada García Cuesta
Jan 3, 2008·Physical Chemistry Chemical Physics : PCCP·Gábor Lente
Mar 28, 2009·Science·Tsuneomi KawasakiKenso Soai
Sep 24, 2015·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Emerson Boscheto, Alejandro López-Castillo
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Oct 23, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Michael Mauksch, Svetlana B Tsogoeva
Oct 6, 2010·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Jean-Claude MicheauThomas Buhse
Aug 31, 2010·Chirality·Luciano CagliotiGyula Pályi
Oct 16, 2013·Angewandte Chemie·Andrew J Bissette, Stephen P Fletcher
Jan 23, 2014·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Kenso SoaiArimasa Matsumoto
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Jan 19, 2019·Organic & Biomolecular Chemistry·Shinobu MiyagawaTsuneomi Kawasaki
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Sep 14, 2007·The Journal of Physical Chemistry. B·Béla BarabasGyula Pályi

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