SrB5 O7 F3 Functionalized with [B5 O9 F3 ]6- Chromophores: Accelerating the Rational Design of Deep-Ultraviolet Nonlinear Optical Materials

Angewandte Chemie
Miriding MutailipuShilie Pan

Abstract

Fluorooxoborates, benefiting from the large optical band gap, high anisotropy, and ever-greater possibility to form non-centrosymmetric structures activated by the large polarization of [BOx F4-x ](x+1)- building blocks, have been considered as the new fertile fields for searching the ultraviolet (UV) and deep-UV nonlinear optical (NLO) materials. Herein, we report the first asymmetric alkaline-earth metal fluorooxoborate SrB5 O7 F3 , which is rationally designed by taking the classic Sr2 Be2 B2 O7 (SBBO) as a maternal structure. Its [B5 O9 F3 ]6- fundamental building block with near-planar configuration composed by two edge-sharing [B3 O6 F2 ]5- rings in SrB5 O7 F3 has not been reported in any other borates. Solid state 19 F and 11 B magic-angle spinning NMR spectroscopy verifies the presence of covalent B-F bonds in SrB5 O7 F3 . Property characterizations reveal that SrB5 O7 F3 possesses the optical properties required for deep-UV NLO applications, which make SrB5 O7 F3 a promising crystal that could produce deep-UV coherent light by the direct SHG process.

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Nov 23, 2017·Journal of the American Chemical Society·Miriding MutailipuShilie Pan

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Citations

Apr 11, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian-Han ZhangJiang-Gao Mao
Jun 5, 2018·Chemistry : a European Journal·Shujuan HanShilie Pan
Jun 6, 2018·Angewandte Chemie·Guopeng HanShilie Pan
Jul 13, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Dequan JiangShilie Pan
Jun 26, 2018·Chemistry : a European Journal·Zhizhong ZhangShilie Pan
Sep 19, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhen JiaMingjun Xia
Nov 13, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·S J HanH H Yu
Jul 19, 2018·Chemistry : a European Journal·Guopeng HanShilie Pan
Jan 12, 2019·Chemical Communications : Chem Comm·Miriding MutailipuShilie Pan
Feb 13, 2019·Chemistry : a European Journal·Yi YangZheshuai Lin
May 8, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Chunmei HuangShilie Pan
Apr 2, 2019·Chemistry : a European Journal·Chunmei HuangShilie Pan
Jun 19, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Ying-Jie JiaXian-Ming Zhang
Aug 2, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jinjie ZhouYicheng Wu
Aug 8, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Abudukadi TudiShilie Pan
Aug 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Qi WuYanjun Li
Nov 26, 2019·Chemical Communications : Chem Comm·Guangmao LiShilie Pan
Oct 18, 2019·Chemistry, an Asian Journal·Qingran DingJunhua Luo
Jan 28, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Guang-Mao LiZhong-Xiang Zhou
Jan 9, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhaohong MiaoShilie Pan
Feb 27, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Xinyuan ZhouXin Su
Feb 20, 2020·Chemical Communications : Chem Comm·Minqiang GaiShilie Pan
Nov 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Chong-An ChenGuo-Yu Yang
Apr 15, 2020·Physical Chemistry Chemical Physics : PCCP·Xiang-Hui LiZhi-Ru Li
Apr 15, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhonglei WeiShilie Pan
May 7, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Ming WenShilie Pan
Jun 20, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun SunShilie Pan
Aug 11, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Wenyao ZhangShilie Pan
Aug 25, 2020·Physical Chemistry Chemical Physics : PCCP·Jingmei MinZhihua Yang

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