Stabilized naked sub-nanometric Cu clusters within a polymeric film catalyze C-N, C-C, C-O, C-S, and C-P bond-forming reactions

Journal of the American Chemical Society
Judit Oliver-MeseguerAvelino Corma

Abstract

Sub-nanometric Cu clusters formed by endogenous reduction of Cu salts and Cu nanoparticles are active and selective catalysts for C-N, C-C, C-O, C-S, and C-P bond-forming reactions. Sub-nanometric Cu clusters have also been generated within a polymeric film and stored with full stability for months. In this way, they are ready to be used on demand and maintain high activity (TONs up to 10(4)) and selectivity for the above reactions. A potential mechanism for the formation of the sub-nanometric clusters and their electronic nature is presented.

References

Jun 20, 2002·Journal of the American Chemical Society·Artis KlaparsStephen L Buchwald
Mar 24, 2005·Journal of the American Chemical Society·Eric R StrieterStephen L Buchwald
Dec 17, 2008·Journal of the American Chemical Society·Eric R StrieterStephen L Buchwald
Jun 26, 2009·Angewandte Chemie·Per-Fredrik LarssonCarsten Bolm
Apr 15, 2010·Journal of the American Chemical Society·Gavin O JonesStephen L Buchwald
Jul 28, 2010·Chemical Communications : Chem Comm·Apoorva KulkarniBruce C Gates
Nov 5, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Elena SperottoJohannes G de Vries
Jan 1, 2010·Chemical Science·David S Surry, Stephen L Buchwald

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Citations

Jan 6, 2017·Chemical Communications : Chem Comm·Judit Oliver-MeseguerAvelino Corma
Dec 3, 2016·Chemistry : a European Journal·Miguel A Rivero-CrespoAvelino Corma
Jan 20, 2017·Chemical Society Reviews·Dong Wang, Didier Astruc
Nov 23, 2017·Nature Communications·Jesús CordónMiguel Monge
Oct 25, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·A Leyva-Pérez
May 5, 2018·Chemical Communications : Chem Comm·Shunmin DingSheng Dai
Oct 19, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Wanli ZhouJun Peng
Oct 15, 2019·Physical Chemistry Chemical Physics : PCCP·Haohao WangFumitaka Mafuné
Jul 17, 2020·Journal of the American Chemical Society·Sanghwa LeeTaeghwan Hyeon
Sep 23, 2021·Physical Chemistry Chemical Physics : PCCP·Máté SzalayTibor Höltzl

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