Stereoinduction in Metallaphotoredox Catalysis.

Angewandte Chemie
Alexander LippGary A Molander

Abstract

Metallaphotoredox catalysis has evolved into an enabling platform to construct C(sp3 )-hybridized centers under remarkably mild reaction conditions. The cultivation of abundant radical precursor feedstocks has significantly increased the scope of transition-metal-catalyzed cross-couplings, especially with respect to C(sp2 )-C(sp3 ) linkages. In recent years, considerable effort has been devoted to understanding the origin of stereoinduction in dual catalytic processes. In this context, Ni- and Cu-catalyzed transformations have played a predominant role exploiting this mode of catalysis. Herein, we provide a critical overview on recent progress in enantioselective bond formations enabled by Ni- and Cu-catalyzed manifolds. Furthermore, selected stereochemical control elements within the realm of diastereoselective transformations are discussed.

References

Apr 8, 2006·Science·Kamil Godula, Dalibor Sames
Oct 16, 2009·Journal of Medicinal Chemistry·Frank LoveringChristine Humblet
Feb 5, 2015·Journal of the American Chemical Society·David N PrimerGary A Molander
Feb 27, 2015·Journal of the American Chemical Society·Yang Zhao, Daniel J Weix
Jul 15, 2015·Journal of the American Chemical Society·Gilbert J Choi, Robert R Knowles
Feb 6, 2016·Journal of the American Chemical Society·Zhiwei ZuoDavid W C MacMillan
Feb 26, 2016·Science·Quirin M KainzGregory C Fu
Apr 26, 2016·Chemical Reviews·Kazimer L SkubiTehshik P Yoon
Sep 23, 2016·Journal of the American Chemical Society·Drew R HeitzGary A Molander
Sep 23, 2016·Journal of the American Chemical Society·Benjamin J Shields, Abigail G Doyle
Dec 10, 2016·Journal of the American Chemical Society·Fei WangGuosheng Liu
Dec 22, 2016·Journal of the American Chemical Society·Wei DingWen-Jing Xiao
Jan 7, 2017·Chemical Science·Derek T Ahneman, Abigail G Doyle
Aug 12, 2017·Chemical Society Reviews·Marvin Parasram, Vladimir Gevorgyan
Oct 19, 2017·Journal of the American Chemical Society·Dinghai WangGuosheng Liu
Feb 13, 2018·Chemical Communications : Chem Comm·Vladimir O SmirnovAlexander D Dilman
Mar 25, 2018·Angewandte Chemie·Audrey DumoulinGary A Molander
Mar 27, 2018·Angewandte Chemie·Shorouk O BadirGary A Molander
May 15, 2018·Journal of the American Chemical Society·Jacob A KautzkyDavid W C MacMillan
Sep 6, 2018·Journal of the American Chemical Society·Yangyang ShenRuben Martin
Sep 15, 2018·Journal of the American Chemical Society·J Luca SchwarzFrank Glorius
Oct 7, 2018·Angewandte Chemie·John A MilliganGary A Molander
Dec 6, 2018·Journal of the American Chemical Society·Russell T SmithDavid W C MacMillan
Apr 2, 2019·Journal of the American Chemical Society·Fu-Dong LuWen-Jing Xiao
May 3, 2019·Science·Asik HossainOliver Reiser
Aug 9, 2019·Nature Communications·Xiaokai ChengZhan Lu
Sep 19, 2019·Angewandte Chemie·Eugenio GandolfoPaolo Melchiorre
Oct 2, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jasmin BuschClaudia Bizzarri
Oct 29, 2019·Accounts of Chemical Research·Qiang-Shuai GuXin-Yuan Liu

❮ Previous
Next ❯

Citations

Aug 20, 2020·Organic & Biomolecular Chemistry·Yukiya SatoHirohisa Ohmiya
Mar 12, 2021·Journal of the American Chemical Society·Fu-Dong LuWen-Jing Xiao
Oct 31, 2020·Journal of the American Chemical Society·Xiaomin ShuHaohua Huo
Apr 29, 2021·Organic & Biomolecular Chemistry·Andrea GualandiPier Giorgio Cozzi
Jun 12, 2021·Nature Communications·Leitao HuanHaohua Huo
Jul 8, 2021·Chemical Reviews·Spencer P Pitre, Larry E Overman
Sep 9, 2021·Chemical Communications : Chem Comm·Antonio PulcinellaTimothy Noël
Aug 19, 2021·Angewandte Chemie·Min ZhengHongjian Lu
Sep 21, 2021·Journal of the American Chemical Society·Sii Hong LauAbigail G Doyle
Oct 13, 2021·Organic Letters·Xiao-Di SuXiang-Yu Chen
Sep 10, 2021·Chemistry : a European Journal·Dmitriy M VolochnyukOleksandr O Grygorenko
Oct 29, 2021·Organic & Biomolecular Chemistry·Wu ZhangHaohua Huo

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.