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Stereoselective aminoacylation of a dinucleoside monophosphate by the imidazolides of DL-alanine and N-(tert-butoxycarbonyl)-DL-alanine

Journal of Molecular Evolution

Jan 1, 1984

A T Profy, David A Usher

PMID: 6433033

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Abstract

The aminoacylation of diinosine monophosphate (IpI) was studied. When the acylating agent was the imidazolide of N-(tert-butoxycarbonyl)-DL-alanine, a 40% enantiomeric excess of the L isomer was incorporated at the internal 2' site and the positions of equilibrium for the 2' in equilibr...read more

Mentioned in this Paper

Oligonucleotides
Abufne
Origin of Life
diinosine monophosphate
Sodium Inosinate
Genetic Code
tertiary-butyloxycarbonyl-alanine imidazolide
Imidazoles
Acylation
Molecular Stereochemistry
Paper Details
References
  • References31
  • Citations17
12

Stereoselective aminoacylation of a dinucleoside monophosphate by the imidazolides of DL-alanine and N-(tert-butoxycarbonyl)-DL-alanine

Journal of Molecular Evolution

Jan 1, 1984

A T Profy, David A Usher

PMID: 6433033

DOI:

Abstract

The aminoacylation of diinosine monophosphate (IpI) was studied. When the acylating agent was the imidazolide of N-(tert-butoxycarbonyl)-DL-alanine, a 40% enantiomeric excess of the L isomer was incorporated at the internal 2' site and the positions of equilibrium for the 2' in equilibr...read more

Mentioned in this Paper

Oligonucleotides
Abufne
Origin of Life
diinosine monophosphate
Sodium Inosinate

Related Papers

Paper Details
References
  • References31
  • Citations17
12

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