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Stereoselective aminoacylation of a dinucleoside monophosphate by the imidazolides of DL-alanine and N-(tert-butoxycarbonyl)-DL-alanine

Journal of Molecular Evolution

Jan 1, 1984

A T Profy, D A Usher

PMID: 6433033

Abstract

The aminoacylation of diinosine monophosphate (IpI) was studied. When the acylating agent was the imidazolide of N-(tert-butoxycarbonyl)-DL-alanine, a 40% enantiomeric excess of the L isomer was incorporated at the internal 2' site and the positions of equilibrium for the 2' in equilibr...read more

Mentioned in this Paper

Abufne
Imidazoles
Inosine
Inosine Nucleotides
Oligonucleotides
Molecular Stereochemistry
Sodium Inosinate
Origin of Life
diinosine monophosphate
Acylation
Paper Details
References
  • References32
  • Citations20
12

Stereoselective aminoacylation of a dinucleoside monophosphate by the imidazolides of DL-alanine and N-(tert-butoxycarbonyl)-DL-alanine

Journal of Molecular Evolution

Jan 1, 1984

A T Profy, D A Usher

PMID: 6433033

DOI:

Abstract

The aminoacylation of diinosine monophosphate (IpI) was studied. When the acylating agent was the imidazolide of N-(tert-butoxycarbonyl)-DL-alanine, a 40% enantiomeric excess of the L isomer was incorporated at the internal 2' site and the positions of equilibrium for the 2' in equilibr...read more

Mentioned in this Paper

Abufne
Imidazoles
Inosine
Inosine Nucleotides
Oligonucleotides
Molecular Stereochemistry
Sodium Inosinate
Origin of Life
diinosine monophosphate
Acylation
Paper Details
References
  • References32
  • Citations20
12
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