Stimuli-Responsive Room-Temperature N-Heteroacene Liquid: In Situ Observation of the Self-Assembling Process and Its Multiple Properties

ACS Applied Materials & Interfaces
Kyosuke IsodaDaisuke Matsukuma

Abstract

A novel stimuli-responsive room-temperature photoluminescent liquid 1 based on the N-heteroacene framework is developed and analyzed by several experiments such as differential scanning calorimetry, X-ray diffraction, dynamic viscoelasticity measurement, in situ observation by optical and polarized optical microscopes, UV-vis absorption and fluorescence spectroscopy, and by theoretical methods such as ab initio calculation and molecular dynamics (MD) computer simulation techniques. In contrast to stimuli-responsive solid materials reported previously, liquid 1 in response to HCl vapor as a single stimulus can involve dramatically multiple changes in physical properties such as rheological behavior, morphology, as well as photoluminescence. The present ab initio calculation and microsecond-timescale MD simulations reveal that the complexation of 1 and HCl molecules induces a large dipole moment, leading to the formation of stacking structures because of their dipole-dipole interaction. Upon exposure to HCl vapor, in situ microscopic observation of the stimuli-responsive liquid elucidates a self-assembling process involving the formation of the wrinkle structure in a micrometer scale, indicating disorder-order phase transition. F...Continue Reading

References

Mar 1, 1985·Physical Review A: General Physics·W G Hoover
Dec 20, 2002·Angewandte Chemie·Thomas Steiner
Sep 12, 2003·Nature·Yanlei YuTomiki Ikeda
Apr 14, 2005·Chemical Reviews·Freek J M HoebenAlbertus P H J Schenning
Oct 8, 2005·Journal of Computational Chemistry·David Van Der SpoelHerman J C Berendsen
Dec 15, 2005·Angewandte Chemie·Takashi KatoKenji Kishimoto
Jan 26, 2007·Journal of the American Chemical Society·Yoshimitsu SagaraKoji Araki
Apr 13, 2007·Chemical Reviews·Amanda R Murphy, Jean M J Fréchet
Nov 7, 2007·Journal of the American Chemical Society·Andrew J BoydstonChristopher W Bielawski
Jan 17, 2008·Chemical Society Reviews·Natalia V Plechkova, Kenneth R Seddon
Jul 25, 2009·Nature Materials·Michel ArmandBruno Scrosati
Jan 23, 2010·Nature Materials·Martien A Cohen StuartSergiy Minko
Nov 1, 2009·Nature Chemistry·Yoshimitsu Sagara, Takashi Kato
Mar 15, 2011·Chemical Communications : Chem Comm·Ka Yi YungGary A Baker
Aug 13, 2011·Advanced Materials·Hyun Suk Kim, Alfred J Crosby
Jan 27, 2012·Angewandte Chemie·Sukumaran Santhosh BabuAyyappanpillai Ajayaghosh
Feb 22, 2012·Science·T AidaS I Stupp
May 24, 2012·Chemical Society Reviews·Xuzhou YanFeihe Huang
Jun 6, 2013·Nature Communications·Sukumaran Santhosh BabuTakashi Nakanishi
Jul 3, 2013·Journal of the American Chemical Society·Kazuhiko NaguraShigehiro Yamaguchi
Aug 27, 2013·Chemical Communications : Chem Comm·Sukumaran Santhosh Babu, Takashi Nakanishi
Dec 18, 2013·Journal of the American Chemical Society·Pengfei DuanNobuo Kimizuka
Jun 18, 2014·Accounts of Chemical Research·Zhenhui Qi, Christoph A Schalley
Apr 23, 2015·Nature Communications·Xisen HouJ Fraser Stoddart
Jun 19, 2015·Nature Communications·Emi UchidaYasuo Norikane
Jul 20, 2016·ACS Applied Materials & Interfaces·Clémence AllainPierre Audebert
Feb 9, 2017·Chemical Communications : Chem Comm·Takashi MachidaKenta Kokado
Feb 16, 2017·Advanced Materials·Hu WangFeihe Huang
Mar 17, 2017·Annual Review of Physical Chemistry·Tatsuya Ishiyama, Akihiro Morita
Apr 22, 2017·Advanced Materials·Songshan ZengLuyi Sun
Jul 29, 2017·Chemical Reviews·Lucas Montero de EspinosaChristoph Weder
Sep 2, 2017·Chemical Communications : Chem Comm·Avijit Ghosh, Takashi Nakanishi
Sep 28, 2017·Physical Chemistry Chemical Physics : PCCP·B NarayanT Nakanishi
Nov 11, 2017·Physical Chemistry Chemical Physics : PCCP·Fengniu LuYuki Kurashige
Oct 9, 2018·Chemical Science·Fengniu LuTakashi Nakanishi
Jan 8, 2019·Journal of the American Chemical Society·Tomoki OgoshiMotohiro Mizuno
Aug 5, 2005·Soft Matter·Takuya OhzonoMasatsugu Shimomura

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Citations

Nov 10, 2020·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Kyosuke Isoda, Yuya Orita
Mar 19, 2021·The Journal of Physical Chemistry Letters·Yuika SatoKyosuke Isoda
Nov 5, 2020·Langmuir : the ACS Journal of Surfaces and Colloids·Mitsuhiko MorisueSono Sasaki
Sep 29, 2021·ACS Applied Materials & Interfaces·Ayumi IkenagaKyosuke Isoda

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