Stoichiometric and catalytic Si-N bond formation using the p-block base Al(NMe2)3

Dalton Transactions : an International Journal of Inorganic Chemistry
Lucy K AllenDominic S Wright

Abstract

The aluminium amide Al(NMe2)3 acts as a stoichiometric or catalytic reagent in dehydrogenic Si-N bond formation using amines and silanes. Although of limited substrate scope, this represents the first p-block metal catalytic system for N-H/Si-H dehydrocoupling. The observed catalytic rate law for the formation of aminosilane products in a model study of one of the catalytic reactions suggests a mechanism involving the silane component in the deprotonation of the amine (possibly in the form of a hypervalent silicon hydride).

References

Mar 21, 2006·Angewandte Chemie·Frank BuchSjoerd Harder
Feb 24, 2010·Chemical Communications : Chem Comm·Alexander J M Miller, John E Bercaw
Jun 4, 2010·Chemical Communications : Chem Comm·Vesal NaseriDominic S Wright
Jun 15, 2010·Chemistry : a European Journal·David J LiptrotDugald J MacDougall
Apr 23, 2011·Chemical Communications : Chem Comm·Robert J LessDominic S Wright
Oct 1, 2011·Journal of the American Chemical Society·James F DunneAaron D Sadow
Jun 27, 2013·Journal of the American Chemical Society·Thomas W Myers, Louise A Berben
Jan 22, 2014·Chemical Communications : Chem Comm·Lutz GrebJan Paradies
Feb 28, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Robert J LessDominic S Wright
Jul 9, 2014·Proceedings of the National Academy of Sciences of the United States of America·Manuel PérezDouglas W Stephan
Jul 12, 2014·Chemical Communications : Chem Comm·Adi E NakoMark R Crimmin

❮ Previous
Next ❯

Citations

Apr 13, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ashim BaishyaSharanappa Nembenna
Jan 25, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Karla A EricksonRory Waterman
Jun 30, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Yann Sarazin, Jean-François Carpentier
Dec 8, 2020·Chemistry : a European Journal·Matthew B ReuterRory Waterman
Aug 15, 2019·Inorganic Chemistry·Jin KimYunho Lee

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemical Communications : Chem Comm
Hugh J CowleyDominic S Wright
Dalton Transactions : an International Journal of Inorganic Chemistry
Rebecca L Melen
Dalton Transactions : an International Journal of Inorganic Chemistry
Robert J LessDominic S Wright
Chemical Communications : Chem Comm
Michael S HillThomas P Robinson
© 2021 Meta ULC. All rights reserved