Structural aspects of long-lived C7H8(2+) dications generated by the electron ionization of toluene

The Journal of Physical Chemistry. a
Jana RoithováHelmut Schwarz

Abstract

The structure of the C7H8(2+) dication generated upon electron ionization of toluene is investigated by experimental and theoretical means. For the long-lived C7H8(2+) dication, the experimental findings obtained with a novel SIFT/GIB instrument suggest complete loss of structural integrity corresponding to the toluene structure. Instead, the manifold of C7H8(2+) dications most likely to be formed is assigned to a mixture of the cycloheptatriene dication and ring-protonated benzylium ions.

References

Dec 3, 1990·Physical Review Letters·J A Samson
Aug 27, 2003·European Journal of Mass Spectrometry·Dorina Fati, Bernard Leyh
Apr 20, 2005·The Journal of Chemical Physics·Jana RoithováOdile Dutuit

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Citations

Jan 4, 2007·Chemistry : a European Journal·Jana Roithová, Detlef Schröder
Mar 5, 2011·Chemistry : a European Journal·Emilie-Laure ZinsJana Roithová
Sep 4, 2015·The Review of Scientific Instruments·Joshua J MelkoAlbert A Viggiano
Nov 18, 2014·The Journal of Physical Chemistry. a·Juraj JašíkJana Roithová
Feb 3, 2007·Physical Chemistry Chemical Physics : PCCP·Jana Roithová, Detlef Schröder
Nov 13, 2007·Angewandte Chemie·Fabiane M NachtigallMarcos N Eberlin
Nov 29, 2008·Physical Chemistry Chemical Physics : PCCP·Daniela AscenziStephen D Price
May 12, 2007·Physical Chemistry Chemical Physics : PCCP·Jana Roithová, Detlef Schröder
Aug 5, 2011·Physical Chemistry Chemical Physics : PCCP·Daniela AscenziJana Roithová
May 19, 2006·The Journal of Physical Chemistry. a·Jana RoithováHelmut Schwarz
Apr 28, 2010·The Journal of Physical Chemistry. a·Emilie-Laure Zins, Detlef Schröder
Aug 25, 2009·The Journal of Physical Chemistry. a·Daniela AscenziChristian Alcaraz
Mar 30, 2006·Journal of the American Chemical Society·Jana Roithova, Detlef Schröder

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