Structural Motifs of [Fe(CO2 )n ]- Clusters (n = 3-7)

The Journal of Physical Chemistry. a
Michael C ThompsonJ Mathias Weber

Abstract

We present IR spectra and quantum chemical calculations for anionic iron-CO2 clusters of the form [Fe(CO2)n]- (n = 3-7). All observed clusters have at least two CO2 units strongly bound to the metal atom. These strongly bound iron-CO2 complexes form the core ions of the clusters and are solvated by additional, weakly bound CO2 molecules. Larger clusters show clear infrared signatures of core ion isomers with three CO2 moieties as well. Dominant structural motifs are based on bidentate CO2 ligands with Fe-O/Fe-C bonds, oxalate ligands, and metal insertion into a CO bond.

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Sep 4, 2014·The Journal of Physical Chemistry. a·Benjamin J Knurr, J Mathias Weber
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Citations

May 18, 2019·Physical Chemistry Chemical Physics : PCCP·Gaoxiang LiuKit H Bowen
Mar 1, 2018·Annual Review of Physical Chemistry·Leah G DodsonJ Mathias Weber
Sep 13, 2018·Angewandte Chemie·Alice E GreenStuart R Mackenzie
Oct 3, 2018·Physical Chemistry Chemical Physics : PCCP·Kacper BlaziakEinar Uggerud
Aug 9, 2018·The Journal of Physical Chemistry. a·Leah G DodsonJ Mathias Weber
Apr 9, 2019·The Journal of Physical Chemistry. a·Dong YangLing Jiang
Mar 31, 2018·The Journal of Physical Chemistry. a·Michael C Thompson, J Mathias Weber
Apr 3, 2018·The Journal of Physical Chemistry. a·Stephanie M CraigMark A Johnson
Mar 8, 2018·The Journal of Physical Chemistry. a·Leah G DodsonJ Mathias Weber

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