Structural phase transition, equation of state and phase diagram of functional rare earth sesquioxide ceramics (Eu1-xLax)2O3.

Scientific Reports
K A IrshadN V Chandra Shekar

Abstract

The intriguing functional nature of ceramics containing rare earth sesquioxide (RES) is associated with the type of polymorphic structure they crystallize into. They prefer to be in the cubic, monoclinic or hexagonal structure in the increasing order of cation size, RRE. Since the functional properties of these ceramics varies with RRE, temperature and pressure, a systematic investigation delineating the cation size effect is indispensable. In the present work we report the structural stability and compressibility behaviour of the RES ceramics, (Eu1-xLax)2O3, of RESs with dissimilar structure and significant difference in cationic radii. The selected compositions of (Eu1-xLax)2O3 have been studied using the in-situ high pressure synchrotron X-ray diffraction and the structural parameters obtained through Rietveld refinement. The cubic structure, which is stable for 0.95 Å [Formula: see text] RRE [Formula: see text] Å at ambient temperature and pressure (ATP), prefers a cubic to hexagonal transition at high pressures. The biphasic region of cubic and monoclinic structure, which is stable for 0.98 Å [Formula: see text] RRE [Formula: see text] Å at ATP, prefers a cubic/monoclinic to hexagonal transition at high pressures. Further,...Continue Reading

Methods Mentioned

BETA
X-ray

Software Mentioned

BM
eos
GSAS
+ EXPGUI

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