Structure and properties of [(4,6-t Bu2 C6 H2 O)2 Se]2 An(THF)2 , An = U, Np, and their reaction with p-benzoquinone

Chemical Communications : Chem Comm
Alexander J MyersJustin R Walensky

Abstract

The synthesis and characterization of U(iv) and Np(iv) selenium bis(phenolate) complexes are reported. The reaction of two equivalents of the U(iv) complex with p-benzoquinone results in the formation of a U(v)-U(v) species with a bridging reduced quinone. This represents a rare example of high-valent uranium chemistry as well as a rare example of a neptunium aryloxide complex.

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