Study on the preparation of the hierarchical porous CX-TiO2 composites and their selective degradation of PHE solubilized in soil washing eluent

Chemosphere
Aijing WangYan Wu

Abstract

A series of CX-TiO2(Carbon Xerogel- TiO2) composites with a hierarchical porous structure were obtained through the sol-gel method followed by drying and carbonization, and have been applied to treating solubilizing wastewater containing a high concentration of phenanthrene (PHE). The characterizations demonstrated that the CX-TiO2 exhibits a hierarchical porous structure, with particles of carbon and P25 being uniformly in the matrix. Removal efficiency of CX-TiO2 on PHE in soil washing eluent (SWE) were evaluated under ultraviolet (UV) irradiation or dark condition, and P25 was employed as the reference. The results revealed that CX-TiO2(0.2) had the best removal effect on PHE, with the efficiency as high as 97.8% under UV illumination within 15 h. It demonstrated that in the process of PHE removal by CX-TiO2 whether it was under UV illumination or not, the adsorption plays a dominant role in the early stage. The kinetic behavior of PHE adsorption was fitted using the pseudo-first-order and pseudo-second-order, and Langmuir model and Freundlich models were applied to describe the PHE adsorption isotherms. The results indicating that it was a chemical adsorption process, which was influenced by the interaction between PHE and ...Continue Reading

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