Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

Proceedings of the National Academy of Sciences of the United States of America
Maximilian JoostChristopher C Cummins

Abstract

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfinylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expulsion and anthracene formation on heating in the solid state and in solution, releasing SO at mild temperatures (<100 °C). The generated SO was detected in the gas phase by MS and rotational spectroscopy. In solution, 1 allows for SO transfer to organic molecules as well as transition metal complexes.

References

Jun 7, 1967·Journal of the American Chemical Society·H H Wasserman, J R Scheffer
Mar 17, 2000·Science·C T Russell, M G Kivelson
Oct 24, 2001·The Journal of Organic Chemistry·Imad A. Abu-Yousef, David N. Harpp
Oct 27, 2001·Organic Letters·R S GraingerJ W Steed
Sep 2, 2006·Science·Nicholas A PiroChristopher C Cummins
Jan 26, 2007·Chemical Communications : Chem Comm·Marc MillerDavid J Procter
Oct 22, 2009·Journal of the American Chemical Society·Heather A SpinneyChristopher C Cummins
Nov 23, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Wolfdieter A Schenk
Aug 17, 2012·Journal of the American Chemical Society·Alexandra Velian, Christopher C Cummins
Nov 8, 2014·Angewandte Chemie·Lauren E LongobardiDouglas W Stephan
Oct 1, 2015·The Journal of Organic Chemistry·Rainer Herges
Apr 3, 2016·The Journal of Chemical Physics·Marie-Aline Martin-DrumelKyle N Crabtree
May 14, 2016·Journal of the American Chemical Society·Wesley J TransueChristopher C Cummins
Dec 14, 2016·Journal of the American Chemical Society·Marc-André CourtemancheChristopher C Cummins
Jul 14, 2017·Journal of the American Chemical Society·Wesley J TransueChristopher C Cummins
Jul 2, 2001·Angewandte Chemie·Lucia BonomoCarlo Floriani

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Citations

Jun 30, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Florenz BußFabian Dielmann
Nov 14, 2018·Physical Chemistry Chemical Physics : PCCP·Jonathon P MisiewiczHenry F Schaefer
Jan 24, 2019·Chemistry : a European Journal·Marie-Aline Martin-DrumelMichael C McCarthy
Jun 4, 2019·The Review of Scientific Instruments·Jessica P PorterfieldMichael C McCarthy
Jun 20, 2020·Angewandte Chemie·Philipp HoltkampNorbert W Mitzel
Aug 2, 2019·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Sergei V MakarovAnna S Makarova
Jun 22, 2021·Inorganic Chemistry·Wesley J TransueChristopher C Cummins

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