Supercritical hydrogenation and acid-catalysed reactions "without gases"

Chemical Communications : Chem Comm
Jason R Hyde, Martyn Poliakoff

Abstract

The high temperature catalytic decomposition of HCO2H and HCO2Et are used to generate the high pressure H2 and the supercritical fluids needed for micro-scale hydrogenation of organic compounds; our approach overcomes the problems and limitations of handling high pressure gases on a small-scale and opens the way to the widespread use of continuous supercritical reactions in the laboratory.

References

Feb 19, 2002·Chemical Reviews·Alfons Baiker

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Citations

Aug 30, 2008·Chemical Communications : Chem Comm·Mohammad S YalfaniJesus Sueiras
Jul 26, 2008·Chemical Communications : Chem Comm·Xiaochun ZhouTianhong Lu
Dec 3, 2014·Biotechnology Advances·Simon K-M R RittmannSung Gyun Kang
Feb 21, 2009·Chemistry : a European Journal·Céline FellayGábor Laurenczy
Apr 23, 2010·Chemistry, an Asian Journal·Tahseen Razzaq, C Oliver Kappe
Aug 22, 2013·Chemical Communications : Chem Comm·Andrew F DalebrookGábor Laurenczy
Feb 22, 2011·ChemSusChem·Muhammad IrfanC Oliver Kappe
Sep 11, 2008·ChemSusChem·Stephan Enthaler
Jun 17, 2010·Journal of the American Chemical Society·Albert BoddienMatthias Beller
Mar 5, 2014·Langmuir : the ACS Journal of Surfaces and Colloids·Koushik BhowmikGoutam De

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