Surface confined synthesis of porphyrin containing two-dimensional polymers: the effect of rigidity and preferential adsorption of building blocks

Chemical Communications : Chem Comm
Xiuling SunShengbin Lei

Abstract

We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.

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Citations

Nov 9, 2016·Chemical Communications : Chem Comm·Lei YuDong Wang
May 23, 2019·Physical Chemistry Chemical Physics : PCCP·Jinwen HuanQingdao Zeng
Jun 13, 2019·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Lili CaoShengbin Lei
Jan 19, 2018·Journal of Physics. Condensed Matter : an Institute of Physics Journal·Marco Di Giovannantonio, Giorgio Contini
Mar 7, 2020·Chemical Society Reviews·Daling CuiFederico Rosei
Jun 12, 2019·Journal of the American Chemical Society·Mary-Ambre CarvalhoRomain Ruppert
Jan 23, 2020·Chemical Reviews·Keyu GengDonglin Jiang
Dec 2, 2021·Chemical Reviews·Austin M EvansWilliam R Dichtel

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