Switching the Mallory Reaction to Synthesis of Naphthalenes, Benzannulated Heterocycles, and Their Derivatives.

The Journal of Organic Chemistry
Andrey G Lvov

Abstract

This review analyzes the new life of a long-known reaction, the photocyclization of diarylethenes, which became a classical tool for the synthesis of phenanthrenes and their heterocyclic analogues (Mallory reaction). It has been shown in recent years that certain diarylethenes undergo photorearrangement to naphthalenes, benzannulated heterocycles, or related products with bicyclic unit. Herein, I analyze how the Mallory reaction path can be altered to obtain bicyclic rather than tricyclic products. The mechanistic aspects and scope of the reaction are discussed.

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Citations

Jul 28, 2021·The Journal of Organic Chemistry·Anton V YadykovValerii Z Shirinian
Oct 13, 2021·The Journal of Organic Chemistry·Andrey N KomogortsevConstantine V Milyutin
Oct 29, 2021·The Journal of Organic Chemistry·Alexey V ZakharovValerii Z Shirinian

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